Formation of ε-caprolactam via catalytic Beckmann rearrangement using P2O5 in ionic liquids

被引：124

作者：

Ren, RX ^{[1
]}

Zueva, LD ^{[1
]}

Ou, W ^{[1
]}

机构：

[1] Wesleyan Univ, Dept Chem, Max Tishler Lab Organ Chem, Middletown, CT 06459 USA

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 48期

关键词：

epsilon-caprolactam; cyclohexanone oxime; phosphorous pentoxide; ionic liquids;

D O I：

10.1016/S0040-4039(01)01850-0

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Catalytic Beckmann rearrangement of cyclohexanone oxime in ionic liquids using PO, or Eaton's reagent has been investigated. 1-n-Butyl-3-methylimidazolium hexafluorophosphate (bmiPF(6)) gives superior results to those noted by earlier workers. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：8441 / 8443

页数：3

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