Quantitative Analysis of Polymer Additives with MALDI-TOF MS Using an Internal Standard Approach

被引：32

作者：

Schwarzinger, Clemens ^{[1
]}

Gabriel, Stefan ^{[1
]}

Beissmann, Susanne ^{[2
]}

Buchberger, Wolfgang ^{[2
]}

机构：

[1] Johannes Kepler Univ Linz, Inst Chem Technol Organ Mat, A-4040 Linz, Austria

[2] Johannes Kepler Univ Linz, Inst Analyt Chem, A-4040 Linz, Austria

来源：

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY | 2012年 / 23卷 / 06期

关键词：

MALDI; Polymer additives; Quantitative analysis; PYROLYSIS-GAS CHROMATOGRAPHY; FLIGHT MASS-SPECTROMETRY; SYNTHETIC-POLYMERS; SAMPLE PREPARATION; LIQUID-CHROMATOGRAPHY;

D O I：

10.1007/s13361-012-0367-1

中图分类号：

Q5 [生物化学];

学科分类号：

071010 ; 081704 ;

摘要：

MALDI-TOF MS is used for the qualitative analysis of seven different polymer additives directly from the polymer without tedious sample pretreatment. Additionally, by using a solid sample preparation technique, which avoids the concentration gradient problems known to occur with dried droplets and by adding tetraphenylporphyrine as an internal standard to the matrix, it is possible to perform quantitative analysis of additives directly from the polymer sample. Calibration curves for Tinuvin 770, Tinuvin 622, Irganox 1024, Irganox 1010, Irgafos 168, and Chimassorb 944 are presented, showing coefficients of determination between 0.911 and 0.990.

引用

页码：1120 / 1125

页数：6

共 26 条

[1] Investigating the Effect of Mixing Ratio on Molar Mass Distributions of Synthetic Polymers determined by MALDI-TOF Mass Spectrometry using Design of Experiments [J].

Brandt, Heike ;

Ehmann, Thomas ;

Otto, Matthias .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2010, 21 (11) :1870-1875

[2] Quantitative analysis of synthetic polymers using matrix-assisted laser desorption/ionization time-of-flight mass spectrometry [J].

Chen, H ;

He, MY ;

Pei, J ;

He, HF .

ANALYTICAL CHEMISTRY, 2003, 75 (23) :6531-6535

[3] Quantitative estimation of geometric isomers by post-source decay MALDI MS [J].

Cheng, Y ;

Hercules, DM .

MICROCHEMICAL JOURNAL, 2002, 72 (03) :255-267

[4] Identification and quantification of (polymeric) hindered-amine light stabilizers in polymers using pyrolysis-gas chromatography-mass spectrometry and liquid chromatography-ultraviolet absorbance detection-evaporative light scattering detection [J].

Coulier, L ;

Kaal, ER ;

Tienstra, M ;

Hankemeier, T .

JOURNAL OF CHROMATOGRAPHY A, 2005, 1062 (02) :227-238

[5]

Duncan Mark W., 2008, Briefings in Functional Genomics & Proteomics, V7, P355, DOI 10.1093/bfgp/eln041

[6] Polymeric integrated selective enrichment target (ISET) for solid-phase-based sample preparation in MALDI-TOF MS [J].

Ekstrom, Simon ;

Wallman, Lars ;

Helldin, Goran ;

Nilsson, Johan ;

Marko-Varga, Gyorgy ;

Laurell, Thomas .

JOURNAL OF MASS SPECTROMETRY, 2007, 42 (11) :1445-1452

[7] Extending the solvent-free MALDI sample preparation method [J].

Hanton, SD ;

Parees, DM .

JOURNAL OF THE AMERICAN SOCIETY FOR MASS SPECTROMETRY, 2005, 16 (01) :90-93

[8] Rapid identification of stabilisers in polypropylene using time-of-flight mass spectrometry and DART as ion source [J].

Haunschmidt, Manuela ;

Klampfl, Christian W. ;

Buchberger, Wolfgang ;

Hertsens, Robert .

ANALYST, 2010, 135 (01) :80-85

[9] Analysis of polymer additives by matrix-assisted laser desorption ionization/time of flight mass spectrometer using delayed extraction and collision induced dissociation [J].

Hsiao, ST ;

Tseng, MC ;

Chen, YR ;

Her, GR .

JOURNAL OF THE CHINESE CHEMICAL SOCIETY, 2001, 48 (6A) :1017-1027

[10] Investigation of Solvent-Free MALDI-TOFMS Sample Preparation Methods for the Analysis of Organometallic and Coordination Compounds [J].

Hughes, Laura ;

Wyatt, Mark F. ;

Stein, Bridget K. ;

Brenton, A. Gareth .

ANALYTICAL CHEMISTRY, 2009, 81 (02) :543-550

← 1 2 3 →