Visible light induced photocatalytic reaction of rhodamine B dye via 12-tungstosilicic acid in water

被引：12

作者：

Chen, CC

Li, JY

Zhao, W

Zhao, JC ^{[1
]}

Wan, LJ

Xu, YM

机构：

[1] Chinese Acad Sci, Inst Chem, Ctr Mol Sci, Beijing 100080, Peoples R China

[2] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

SCIENCE IN CHINA SERIES B-CHEMISTRY | 2003年 / 46卷 / 06期

关键词：

photocatalysis; polyoxometalates; 12-tungstosilicic acid; rhodamine B; N-deethylation;

D O I：

10.1360/02yb0188

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using 12-tungstosilicic acid (SiW124-) as the catalyst, rhodamine B (RhB) dye in an aerated aqueous solution can undergo an effective photocatalytic stepwise N-deethylation process under visible light irradiation, and dioxygen is reduced to hydrogen peroxide by the reduced SiW124-. This provides the potential for moving polyoxometalate-based photocatalytic processes from the near-UV into the visible region of the spectrum.

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收藏

页码：577 / 582

页数：6

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