4′-functionalized 2,2′:6′,2"-terpyridines as building blocks for supramolecular chemistry and nanoscience

被引：115

作者：

Schubert, US

Eschbaumer, C

Hien, O

Andres, PR

机构：

[1] Eindhoven Univ Technol, Lab Macromol & Organ Chem, NL-5600 MB Eindhoven, Netherlands

[2] Tech Univ Munich, Lehrstuhl Makromol Stoffe, D-85747 Garching, Germany

来源：

TETRAHEDRON LETTERS | 2001年 / 42卷 / 28期

关键词：

D O I：

10.1016/S0040-4039(01)00796-1

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Different mono- and bis-terpyridines were synthesized utilizing nucleophilic substitution of 4 ' -chloro-2,2 ' ;6 ' ,2 " -terpyridine. In the case of the mono-functionalized ligands, different functional groups opposite to the metal binding site could be introduced; with thr bis-functionalized ligands building blocks for metal-containing polymers with a tailored alkyl-chain length were accessible. As examples, a functionalized terpyridine cadmium(II) complex as well as a fullerene derivative were prepared. (C) 2001 Elsevier Science Ltd. All rights reserved.

引用

页码：4705 / 4707

页数：3

共 23 条

[1] SYNTHESIS AND COORDINATION BEHAVIOR OF 6',6''-BIS(2-PYRIDYL)-2,2'-4,4''-2'',2'''-QUATERPYRIDINE - BACK-TO-BACK 2,2'-6',2''-TERPYRIDINE [J].