Synthesis and fluorescence of the new environment-sensitive fluorophore 6-chloro-2,3-naphthalimide derivative

被引：15

作者：

Katritzky, Alan R. ^{[1
]}

Ozcan, Sevil ^{[1
,2
]}

Todadze, Ekaterina ^{[1
]}

机构：

[1] Univ Florida, Dept Chem, Ctr Heterocycl Cpds, Gainesville, FL 32611 USA

[2] Abant Izzet Baysal Univ, Dept Chem, TR-14280 Golkoy, Bolu, Turkey

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2010年 / 8卷 / 06期

关键词：

PROBES;

D O I：

10.1039/c000684j

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Convenient and efficient synthesis of a new environmentally sensitive chlorine-substituted 2,3-naphthalimide-based fluorophore is reported. Benzotriazole carboxyl group activation of the 6-chloro-fluorophore enabled quick labeling of free and Fmoc-protected amino acids. The photophysical properties of the compounds obtained include high quantum yields in solvents of different polarity: water, methanol, acetonitrile and hexane.

引用

页码：1296 / 1300

页数：5

共 46 条

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[45] PURINES PYRIMIDINES AND IMIDAZOLES .28. SYNTHESES OF 9-BETA-D-RIBOFURANOSYLZEATIN 5'-PHOSPHATE A NATURALLY OCCURRING ADENYLIC ACID DERIVATIVE WITH PLANT CELL-DIVISION PROMOTING ACTIVITY AND A NEW SYNTHESIS OF 6-CHLORO-9-BETA-D-RIBOFURANOSYLPURINE 5'-PHOSPHATE
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[46] New 10-membered inorganic heterocyclic diphosphanes, PhN(PX)2{(-OC6H2(tBU)2)(μ-S)(tBu)2C6H2O-)} (X = Cl, F).: Synthesis and transition metal complexes (molybdenum(0), ruthenium(II), palladium(II), and platinum(II)) of heterocyclic diphosphanes.: Crystal and molecular structures of the chloro derivative, PhN(PCl)2](-OC6H2(Bu)2)(μ-S)(tBu)2C6H2O-)}, and of a molybdenum(0) complex of the fluoro derivative, [Mo(CO)3{η3-PhN(PF)2{(-OC6H2(tBu)2)(μ-S)(tBu)2C6H2O-)}-κP,κP,κS}]
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