Rational Synthesis of Mixed-Metal Microporous Metal-Organic Frameworks with Controlled Composition Using Mechanochemistry

被引：98
作者：
Ayoub, Ghada [1 ]
Karadeniz, Bahar [2 ]
Howarth, Ashlee J. [3 ,4 ]
Farha, Omar K. [3 ]
Dilovic, Ivica [5 ]
Germann, Luzia S. [6 ]
Dinnebier, Robert E. [6 ]
Uzarevic, Krunoslav [2 ]
Friscic, Tomislav [1 ,2 ]
机构：
[1] McGill Univ, Dept Chem, 801 Sherbrooke St W, Montreal, PQ H3A 0B8, Canada
[2] Inst Ruder Boskovic, Bijenicka 54, HR-10000 Zagreb, Croatia
[3] Northwestern Univ, Dept Chem, 2145 Sheridan Rd, Evanston, IL 60208 USA
[4] Concordia Univ, Dept Chem & Biochem, Montreal, PQ H4B 1R6, Canada
[5] Univ Zagreb, Dept Chem, Fac Sci, Zagreb 10000, Croatia
[6] Max Planck Inst Solid State Res, D-70569 Stuttgart, Germany
来源：
CHEMISTRY OF MATERIALS | 2019年 / 31卷 / 15期
基金：
加拿大自然科学与工程研究理事会;
关键词：
HIGH-SURFACE-AREA; HYDROGEN ADSORPTION; POROUS MATERIAL; HIGH-CAPACITY; PORE-SIZE; MOF-74; SEPARATIONS; STORAGE; METHANE; DESIGN;
D O I：
10.1021/acs.chemmater.9b01068
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Mechanochemistry enables targeted, rapid synthesis of bimetallic metal-organic frameworks (MOFs) with a controlled 1:1 stoichiometric composition of metal nodes. In particular, ball milling enabled the use of specifically synthesized solid coordination complexes of Zn(II), Mg(II), Ni(II), and Co(II) for the assembly of a range of microporous mixed-metal MOF-74 materials composed of pairs of d-block or main group metals in a predetermined 1:1 stoichiometric ratio, including ZnMg-, ZnCo-, ZnCu-, MgZn-, MgCo-, NiZn-, NiMg-, NiCo-, CoZn-, CoMg-, CoCu-, and MgCa-MOF-74. By using specifically prepared precursors in the synthesis of diverse mixed-metal MOF-74 targets, this rational synthesis represents the first entry of mechano-chemistry into the target-oriented synthesis of mixed-metal MOFs.
引用
收藏
页码：5494 / 5501
页数：8
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