An overview of modeling studies in HDS, HDN and HDO catalysis

被引:174
作者
Angelici, RJ [1 ]
机构
[1] IOWA STATE UNIV,AMES LAB,AMES,IA 50011
关键词
hydrodesulfurization; hydrodenitrogenation; hydrodeoxygenation; thiophene; pyridine; furan;
D O I
10.1016/S0277-5387(96)00581-5
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
Recent legislation directed at reducing sulfur levels in petroleum-based fuels has led to numerous studies of commercial hydrotreating, the process whereby sulfur, nitrogen, and oxygen are removed from organic compounds in petroleum feedstocks. The goal of this overview is to highlight organometallic and clean surface model studies that offer realistic ways of understanding details of hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodeoxygenation (HDO) reactions as they occur on heterogeneous hydrotreating catalysts. (C) 1997 Elsevier Science Ltd.
引用
收藏
页码:3073 / 3088
页数:16
相关论文
共 130 条
[1]   BENZENE AND THIOPHENE FORMATION FROM ACETYLENE ON SULFIDED PD(111) STUDIED BY LITD FTMS [J].
ABDELREHIM, IM ;
THORNBURG, NA ;
SLOAN, JT ;
LAND, DP .
SURFACE SCIENCE, 1993, 298 (01) :L169-L172
[2]   FORMATION OF BUTENETHIOLATE BY THE RING-OPENING OF TETRAHYDROTHIOPHENE BY A TRIOSMIUM CLUSTER COMPLEX [J].
ADAMS, RD ;
POMPEO, MP ;
WU, WG ;
YAMAMOTO, JH .
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1993, 115 (18) :8207-8213
[3]   THE ACTIVATION OF TERTIARY-AMINES BY OSMIUM CLUSTER COMPLEXES - FURTHER-STUDIES OF THE REACTION OF OS3(CO)10(NCME)2 WITH TRIETHYLAMINE [J].
ADAMS, RD ;
TANNER, JT .
APPLIED ORGANOMETALLIC CHEMISTRY, 1992, 6 (05) :449-462
[4]  
Aksenov V.A., 1981, ORGANIC SULFUR CHEM, P201
[5]   SYNTHESIS AND EVALUATION OF THE BONDING PROPERTIES OF 2,5-BIS(2-(DIPHENYLPHOSPHINO)ETHYL)THIOPHENE - A NEW POTENTIALLY TRIDENTATE LIGAND [J].
ALVAREZ, M ;
LUGAN, N ;
MATHIEU, R .
INORGANIC CHEMISTRY, 1993, 32 (25) :5652-5657
[6]  
ANGELICI RJ, 1995, B SOC CHIM BELG, V104, P265
[7]   STRUCTURAL ASPECTS OF THIOPHENE COORDINATION IN TRANSITION-METAL COMPLEXES [J].
ANGELICI, RJ .
COORDINATION CHEMISTRY REVIEWS, 1990, 105 :61-76
[8]   HETEROGENEOUS CATALYSIS OF THE HYDRODESULFURIZATION OF THIOPHENES IN PETROLEUM - AN ORGANOMETALLIC PERSPECTIVE OF THE MECHANISM [J].
ANGELICI, RJ .
ACCOUNTS OF CHEMICAL RESEARCH, 1988, 21 (11) :387-394
[9]  
[Anonymous], ENCY INORGANIC CHEM
[10]  
[Anonymous], HYDROTREATING CATALY