Solvent- and Metal-free Oxidative Esterification of Aromatic Aldehydes Using Urea-2,2-dihydroperoxypropane as a New Solid Oxidant

被引：6

作者：

Khosravi, Kaveh ^{[1
]}

Khalaji, Kobra ^{[1
]}

Naserifar, Shirin ^{[1
]}

机构：

[1] Arak Univ, Dept Chem, Fac Sci, Arak 3815688349, Iran

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2017年 / 64卷 / 03期

关键词：

Oxidative esterification; Aromatic aldehydes; gem-Dihydroperoxide; Urea-2; 2-dihydroperoxypropane; HBr; ANTIMALARIAL ACTIVITY; DIRECT CONVERSION; ESTERS; ALCOHOLS; ACIDS; PEROXIDES; CATALYST; KETONES; NHC;

D O I：

10.1002/jccs.201600777

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Urea-2,2-dihydroperoxypropane as a noble and solid gem-dihydroperoxide derivative was used to transform various aromatic aldehydes to their corresponding benzoate derivatives in the presence of HBr under mild conditions at room temperature in high yields and short reaction times.

引用

页码：303 / 309

页数：7

共 62 条

[1] KMNO4 REVISITED - OXIDATION OF ALDEHYDES TO CARBOXYLIC-ACIDS IN THE TERT-BUTYL ALCOHOL AQUEOUS NAH2PO4 SYSTEM
ABIKO, A
ROBERTS, JC
TAKEMASA, T
MASAMUNE, S
[J]. TETRAHEDRON LETTERS, 1986, 27 (38) : 4537 - 4540
[2] Design and synthesis of orally active dispiro 1,2,4,5-tetraoxanes; synthetic antimalarials with superior activity to artemisinin
Amewu, Richard
Stachulski, Andrew V.
Ward, Stephen A.
Berry, Neil G.
Bray, Patrick G.
Davies, Jill
Labat, Gael
Vivas, Livia
O'Neill, Paul M.
[J]. ORGANIC & BIOMOLECULAR CHEMISTRY, 2006, 4 (24) : 4431 - 4436
[3] [Anonymous], ADV ORGANIC CHEM REA
[4] [Anonymous], 2005, ESTERS ORGANIC ULLMA, DOI DOI 10.1002/14356007.A09_565.PUB2
[5] Asgari A., 2015, J ADV CHEM, V11, P3381
[6] Palladium-Catalyzed Carbonylation-A Reaction Come of Age
Barnard, Christopher F. J.
[J]. ORGANOMETALLICS, 2008, 27 (21) : 5402 - 5422
[7] Chavan SP, 2002, SYNLETT, P267
[8] Recent advances in the Mitsunobu reaction: Modified reagents and the quest for chromatography-free separation
Dembinski, R
[J]. EUROPEAN JOURNAL OF ORGANIC CHEMISTRY, 2004, 2004 (13) : 2763 - 2772
[9] Synthesis and Antimalarial Activity of 1,2,4,5-Tetraoxanes
Dong, Yuxiang
[J]. MINI-REVIEWS IN MEDICINAL CHEMISTRY, 2002, 2 (02) : 113 - 123
[10] Bromide ions and methyltrioxorhenium as cocatalysts for hydrogen peroxide oxidations and brominations
Espenson, JH
Zhu, ZL
Zauche, TH
[J]. JOURNAL OF ORGANIC CHEMISTRY, 1999, 64 (04) : 1191 - 1196

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