Highly Efficient Access to Iminoisocoumarins and α-Iminopyrones via AgOTf-Catalyzed Intramolecular Enyne-Amide Cyclization

被引：54

作者：

Bian, Ming ^{[1
]}

Yao, Weijun ^{[1
]}

Ding, Hanfeng ^{[1
]}

Ma, Cheng ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310027, Peoples R China

来源：

JOURNAL OF ORGANIC CHEMISTRY | 2010年 / 75卷 / 01期

关键词：

NITROGEN DOUBLE-BOND; TERMINAL ACETYLENES; ISOMERIZATION; ALKYNES; HETEROCYCLES; CHEMISTRY; ACID; OXAZOLES; IMINES; RULES;

D O I：

10.1021/jo9023478

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Iminoisocoumarins and alpha-iminopyrones are prepared via Sonogashira coupling and AgOTf-catalyzed 6-endo-dig O-cyclization of the enyne-amide system in dichloroethane, in one pot or stepwise, respectively.

引用

页码：269 / 272

页数：4

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