Mechanochemical assembly of hydrogen bonded organic-organometallic solid compounds

被引：50
作者：
Braga, D
Maini, L
Polito, M
Mirolo, L
Grepioni, F
机构：
[1] Univ Bologna, Dipartimento Chim G Ciamician, I-40126 Bologna, Italy
[2] Univ Sassari, Dipartimento Chim, I-07100 Sassari, Italy
来源：
CHEMICAL COMMUNICATIONS | 2002年 / 24期
关键词：
D O I：
10.1039/b209861j
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Solvent-free reactions with molecular systems have been exploited to prepare hybrid organic-organometallic solids: grinding of the complex [Fe(eta(5)-C5H4COOH)(2)] with solid bases B generates quantitatively the corresponding hydrogen bonded salts [Fe(eta(5)-C5H4COOH)(eta(5)-C5H4COO)][HB] (B = 1,4-diazabicyclo[2.2.2]octane, 1,4-phenylenediamine); gas-solid reactions are also possible with volatile bases.
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收藏
页码：2960 / 2961
页数：2
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