Recent advances in chiral imino-containing ligands for metal-catalyzed asymmetric transformations

被引：26

作者：

Chen, Xu ^{[1
]}

Lu, Zhan ^{[1
]}

机构：

[1] Zhejiang Univ, Dept Chem, Hangzhou 310058, Zhejiang, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2017年 / 15卷 / 11期

基金：

中国国家自然科学基金;

关键词：

DIELS-ALDER REACTIONS; 1,3-DIPOLAR CYCLOADDITION REACTIONS; MUKAIYAMA ALDOL REACTIONS; DECARBOXYLATIVE PROPARGYLIC ALKYLATION; COPPER(II)-CATALYZED HENRY REACTION; RUTHENIUM PNNP COMPLEXES; FORMAL 3+2 CYCLOADDITION; SCHIFF-BASE LIGANDS; SALEN-TYPE-LIGANDS; ALLYLIC ALKYLATION;

D O I：

10.1039/c6ob02817a

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

In this review, the recent applications of a variety of chiral imino-containing ligands classified by different types of metal-catalyzed asymmetric reactions are summarized. The progress made in this area would encourage us to design and synthesize more novel chiral imino-containing ligands, and explore their applications in metal-catalyzed asymmetric transformations.

引用

页码：2280 / 2306

页数：27

共 146 条

[1] Asymmetric catalysis of carbon-carbon bond-forming reactions using metal(salen) complexes [J].

Achard, TRJ ;

Clutterbuck, LA ;

North, M .

SYNLETT, 2005, (12) :1828-1847

[2]

Adams E, 1999, J ORG CHEM, V64, P8256

[3] Ruthenium-catalyzed asymmetric electrophilic fluorination of 1,3-dicarbonyl compounds [J].

Althaus, Martin ;

Becker, Claus ;

Togni, Antonio ;

Mezzetti, Antonio .

ORGANOMETALLICS, 2007, 26 (24) :5902-5911

[4] Asymmetric oxidative α-fluorination of 2-alkylphenylacetaldehydes with AgHF2 and ruthenium/PNNP catalysts [J].

Althaus, Martin ;

Togni, Antonio ;

Mezzetti, Antonio .

JOURNAL OF FLUORINE CHEMISTRY, 2009, 130 (08) :702-707

[5] Pyridine-hydrazone ligands in enantioselective palladium-catalyzed Suzuki-Miyaura cross-couplings [J].

Alvarez-Casao, Yolanda ;

Estepa, Beatriz ;

Monge, David ;

Ros, Abel ;

Iglesias-Siguenza, Javier ;

Alvarez, Eleuterio ;

Fernandez, Rosario ;

Lassaletta, Jose M. .

TETRAHEDRON, 2016, 72 (34) :5184-5190

[6] Pyridine-Hydrazones as N,N′-Ligands in Asymmetric Catalysis: Pd(II)-Catalyzed Addition of Boronic Acids to Cyclic Sulfonylketimines [J].

Alvarez-Casao, Yolanda ;

Monge, David ;

Alvarez, Eleuterio ;

Fernandez, Rosario ;

Lassaletta, Jose M. .

ORGANIC LETTERS, 2015, 17 (20) :5104-5107

[7] Chiral salen complexes: An overview to recoverable and reusable homogeneous and heterogeneous catalysts [J].

Baleizao, Carlos ;

Garcia, Hermenegildo .

CHEMICAL REVIEWS, 2006, 106 (09) :3987-4043

[8] Enantioselective addition of phenyl and alkyl acetylenes to imines catalyzed by chiral Cu(I) complexes [J].

Benaglia, M ;

Negri, D ;

Dell'Anna, G .

TETRAHEDRON LETTERS, 2004, 45 (47) :8705-8708

[9] Chiral lutetium benzamidinate complexes [J].

Benndorf, Paul ;

Jenter, Jelena ;

Zielke, Larissa ;

Roesky, Peter W. .

CHEMICAL COMMUNICATIONS, 2011, 47 (09) :2574-2576

[10] C2-Symmetric Bis-Hydrazones as Ligands in the Asymmetric Suzuki-Miyaura Cross-Coupling [J].

Bermejo, Antonio ;

Ros, Abel ;

Fernandez, Rosario ;

Lassaletta, Jose M. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (47) :15798-+

← 1 2 3 4 5 6 7 8 9 10 →