Structural, Magnetic and Optical Properties of Gd and Co Co-Doped YFeO3 Nanopowders

被引:35
作者
Wang, Meng [1 ]
Wang, Ting [2 ]
机构
[1] Shenzhen Polytech, Sch Mech & Elect Engn, Shenzhen 518055, Peoples R China
[2] Harbin Inst Technol, Shenzhen Grad Sch, Dept Mat Sci & Engn, Shenzhen Key Lab Adv Mat, Shenzhen 518055, Peoples R China
关键词
multiferroics; low-temperature solid-state reaction; optical properties; magnetic properties; co-doping; SUBSTITUTION; TEMPERATURE; COMBUSTION;
D O I
10.3390/ma12152423
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
YFeO3, YFe0.95Co0.05O3, Y0.95Gd0.05FeO3 and Y1-xGdxFe0.95Co0.05O3 (x = 0.0, 0.05, 0.10, 0.15 and 0.20) nanopowders were successfully fabricated via a low-temperature solid-state reaction technique. Results obtained using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectra indicate that YFeO3 nanopowders with Gd3+ and Co3+ ions co-doping at Y and Fe-sites were fabricated at 800 degrees C in sizes below 50 nm, and a distorted structure was obtained. Magnetic hysteresis loop analyses illustrate that ferromagnetic behavior of YFeO3 nanopowders can be enhanced with the addition of Gd and Co. Whereas the maximum and remnant magnetization of the powders were found to be about 5.24 and 2.6 emu/g, respectively, the optical band gap was around 2.4 eV, proving that co-doped YFeO3 nanopowders have a strong capability to absorb visible light. Because both magnetic and optical properties of these materials are greatly improved with the addition of Gd and Co, one can expect the scope of their potential application in the magnetic and optical fields to increase.
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页数:11
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