A 3D 2-fold interpenetrating Cu(II) coordination polymer based on 4,4′-oxybis(benzoic acid) and 1,3-bis(2-methyl-imidazol-1-yl) benzene exhibiting photocatalytic properties

被引:0
作者
Qiao, Shan-Bao [1 ]
机构
[1] Yancheng Teachers Univ, Sch Chem & Environm Engn, Yancheng 224007, Jiangsu, Peoples R China
来源
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2021年 / 76卷 / 3-4期
关键词
1,3-bis(2-methyl-1H-imidazol-1-yl)benzene; co-ordination polymers; 2-fold interpenetrating structure; 4,4 '-oxybis(benzoic acid); photocatalytic activity; METAL-ORGANIC FRAMEWORKS; LUMINESCENT;
D O I
10.1515/znb-2020-0085
中图分类号
O61 [无机化学];
学科分类号
070301 ; 081704 ;
摘要
A new Cu(II) complex, [Cu-2(1,3-BMIB)(OBA)(2)](n), (1) (1,3-BMIB = 1,3-bis(2-methyl-1H-imidazol-1-yl)benzene, H(2)OBA = 4,4'-oxybis(benzoic acid)) was hydrothermally synthesized and has been structurally characterized. Complex 1 possesses a 3D 2-fold interpenetrating framework based on [Cu(OBA)](n) layers with a Schlafli symbol {4(12).6(3)}. Complex 1 displays excellent photocatalytic properties in the degradation of methylene blue (MB) and rhodamine B (RhB).
引用
收藏
页码:237 / 241
页数:5
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