Beyond ketonization: selective conversion of carboxylic acids to olefins over balanced Lewis acid-base pairs

被引：41

作者：

Baylon, Rebecca A. L. ^{[1
]}

Sun, Junming ^{[1
]}

Martin, Kevin J. ^{[2
]}

Venkitasubramanian, Padmesh ^{[2
]}

Wang, Yong ^{[1
,3
]}

机构：

[1] Washington State Univ, Gene & Linda Voiland Sch Chem Engn & Bioengn, Pullman, WA 99164 USA

[2] Archer Daniels Midland Co, 1001 N Brush Coll Rd, Decatur, IL 62521 USA

[3] Pacific NW Natl Lab, Inst Integrated Catalysis, Richland, WA 99352 USA

来源：

CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 28期

关键词：

CATALYTIC CONVERSION; HZSM-5; ZEOLITE; MIXED OXIDES; ACETIC-ACID; BIO-ETHANOL; ACETONE; ISOBUTENE; BIOMASS; CHEMISTRY; ZNXZRYOZ;

D O I：

10.1039/c5cc10528e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

We report the direct conversion of mixed carboxylic acids to C-3(=)-C-6(=) olefins with up to 60 mol% carbon yield through cascade (cross) ketonization, (cross) aldolization and self-deoxygenation reactions. Co-feeding hydrogen provides an additional ketone hydrogenation/dehydration pathway to a wider range of olefins.

引用

页码：4975 / 4978

页数：4

共 25 条

[1] A C-13 NMR-STUDY OF THE CONDENSATION CHEMISTRY OF ACETONE AND ACETALDEHYDE ADSORBED AT THE BRONSTED ACID SITES IN H-ZSM-5 [J].

BIAGLOW, AI ;

SEPA, J ;

GORTE, RJ ;

WHITE, D .

JOURNAL OF CATALYSIS, 1995, 151 (02) :373-384

[2] CONVERSION OF METHANOL AND OTHER O-COMPOUNDS TO HYDROCARBONS OVER ZEOLITE CATALYSTS [J].

CHANG, CD ;

SILVESTRI, AJ .

JOURNAL OF CATALYSIS, 1977, 47 (02) :249-259

[3] Cascade Reactions for the Continuous and Selective Production of Isobutene from Bioderived Acetic Acid Over Zinc-Zirconia Catalysts [J].

Crisci, Anthony J. ;

Dou, Herui ;

Prasomsri, Teerawit ;

Roman-Leshkov, Yuriy .

ACS CATALYSIS, 2014, 4 (11) :4196-4200

[4] REACTION OF AMMONIA WITH SURFACE SPECIES FORMED FROM ACETONE ON A HZSM-5 ZEOLITE [J].

DOLEJSEK, Z ;

NOVAKOVA, J ;

BOSACEK, V ;

KUBELKOVA, L .

ZEOLITES, 1991, 11 (03) :244-247

[5] Old acetogens, new light [J].

Drake, Harold L. ;

Goessner, Anita S. ;

Daniel, Steven L. .

INCREDIBLE ANAEROBES: FROM PHYSIOLOGY TO GENOMICS TO FUELS, 2008, 1125 :100-128

[6] Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. H. Aldehydes, ketones, and acids [J].

Gayubo, AG ;

Aguayo, AT ;

Atutxa, A ;

Aguado, R ;

Olazar, M ;

Bilbao, J .

INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2004, 43 (11) :2619-2626

[7] Ethanol for a sustainable energy future [J].

Goldemberg, Jose .

SCIENCE, 2007, 315 (5813) :808-810

[8] Synthesis of transportation fuels from biomass: Chemistry, catalysts, and engineering [J].

Huber, George W. ;

Iborra, Sara ;

Corma, Avelino .

CHEMICAL REVIEWS, 2006, 106 (09) :4044-4098

[9] Production of liquid alkanes by aqueous-phase processing of biomass-derived carbohydrates [J].

Huber, GW ;

Chheda, JN ;

Barrett, CJ ;

Dumesic, JA .

SCIENCE, 2005, 308 (5727) :1446-1450

[10] ACETONE CONVERSION TO ISOBUTENE IN HIGH SELECTIVITY USING ZEOLITE-BETA CATALYST [J].

HUTCHINGS, GJ ;

JOHNSTON, P ;

LEE, DF ;

WILLIAMS, CD .

CATALYSIS LETTERS, 1993, 21 (1-2) :49-53

← 1 2 3 →