Self-assembly of nanometer-scale [Cu24I10L12]14+ cages and ball-shaped Keggin clusters into a (4,12)-connected 3D framework with photoluminescent and electrochemical properties

被引：367

作者：

Wang, Xin-Long ^{[1
]}

Qin, Chao ^{[1
]}

Wang, En-Bo ^{[1
]}

Su, Zhong-Min ^{[1
]}

Li, Yang-Guang ^{[1
]}

Xu, Lin ^{[1
]}

机构：

[1] NE Normal Univ, Dept Chem, Inst Polyoxometalate Chem, Key Lab Polyoxometalate Sci,Minist Educ, Changchun 130024, Jilin, Peoples R China

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2006年 / 45卷 / 44期

关键词：

cluster compounds; copper; molybdenum; N ligands; polyoxometalates;

D O I：

10.1002/anie.200603250

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Bridging two traditional but distinct research areas - polyoxometalate chemistry and cuprous halide clusters - the (4,12)-connected 3D framework (NH4)[Cu24I10L12][PMo V2MoVI10O40]3 has been built by covalent linkage of nanoscale Keggin anions and [Cu 24I10L12]14+ clusters (see picture; L is a multidentate N-heterocyclic ligand); it exhibits remarkable photoluminescent and electrochemical properties. © 2006 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：7411 / 7414

页数：4

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