A facile iodide-controlled fluorescent switch based on the interconversion between two- and three-coordinate copper(I) complexes

被引：16

作者：

Chou, Chang-Chuan ^{[1
]}

Liu, Hsueh-Ju ^{[1
]}

Chao, Lucas Hung-Chieh ^{[1
]}

机构：

[1] Chang Gung Inst Technol, Ctr Gen Educ, Tao Yuan 333, Taiwan

来源：

CHEMICAL COMMUNICATIONS | 2009年 / 42期

关键词：

MOLECULAR MACHINE PROTOTYPES; CARBON-MONOXIDE; MONONUCLEAR; REACTIVITY; TRANSLOCATION; ADDUCTS; BINDING; ION;

D O I：

10.1039/b908765f

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The first paradigm of halide-controlled interconversion between two- and three-coordinate copper(I) complexes, [Cu(L(Ph))](ClO(4)) (1 center dot ClO(4)) and [Cu(L(Ph))I] (2), where L(Ph) = 1,3-bis-(3,5-dimethyl-pyrazol-1-ylmethyl)-2-phenyl-2,3-dihydro-1H-perimidine, was presented, which can result in reversible fluorescence changes.

引用

页码：6382 / 6384

页数：3

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