Solvothermal synthesis, crystal structure and photoluminescent property of a novel 3D cadmium(II) coordination polymer containing [Cd5(μ3-OH)2(μ3-OAc)2]6+ cores

被引：20

作者：

Wang, Ji-Jiang

Yang, Meng-Lin

Hu, Huai-Ming ^{[1
]}

Xue, Gang-Lin

Li, Dong-Sheng

Shi, Qi-Zhen

机构：

[1] NW Univ Xian, Shaanxi Key Lab Physicoinorgan Chem, Dept Chem, Xian 710069, Peoples R China

[2] Yanan Univ, Shaanxi Key Lab Chem React Engn, Dept Chem & Chem Engn, Yanan 716000, Peoples R China

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2007年 / 10卷 / 03期

基金：

中国国家自然科学基金;

关键词：

solvothermal synthesis; crystal structure; coordination polymer; photoluminescent properties;

D O I：

10.1016/j.inoche.2006.10.031

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A novel 3D coordination polymer, ([Cd-5(mu(3)-OAc)(2)(mu(2)-OAc)(2)(mu(3)-OH)(2)(pam)(2)(4,4'-bPY)(2)] (.) CH3CH2OH}(n) (1) (H(2)pam = pamoic acid, HOAc = acetic acid, 4,4'-bpy = 4,4'-bipyridyl), was solvothermally synthesized and characterized by the single crystal X-ray diffraction. The title compound contains unprecedented [Cd-5(mu(3)-OH)(2)(mu(3)-OAc)(2)](6+) pentanuclear building units which are linked through pam and 4,4'-bpy ligands to afford a three-dimensional structure. The infrared spectroscopy, thermal stability and photoluminescence of the complex were studied. (c) 2006 Elsevier B.V. All rights reserved.

引用

页码：269 / 272

页数：4

共 25 条

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