H2O2 generation by decamethylferrocene at a liquid | liquid interface

被引：84

作者：

Su, Bin ^{[1
]}

Nia, Raheleh Partovi ^{[1
]}

Li, Fei ^{[1
]}

Hojeij, Mohamad ^{[1
]}

Prudent, Michel ^{[1
]}

Corminboeuf, Clemence ^{[2
]}

Samec, Zdenek ^{[3
]}

Girault, Hubert H. ^{[1
]}

机构：

[1] Ecole Polytech Fed Lausanne, Lab Electchim Phys & Analyt, CH-1015 Lausanne, Switzerland

[2] Ecole Polytech Fed Lausanne, Lab Computat Mol Design, CH-1015 Lausanne, Switzerland

[3] Acad Sci Czech Republic, J Heyrovsky Inst Phys Chem & Electrochem, Dept Electrochem, CR-18223 Prague, Czech Republic

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2008年 / 47卷 / 25期

关键词：

decamethylferrocene; hydrogen peroxide; interfaces; oxygen; reduction;

D O I：

10.1002/anie.200801004

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Hydrogen peroxide generation at a liquid|liquid interface occurs with a yield of 20% with respect to the concentration of reducing agent (decamethylferrocene). The liquid|liquid interface supplies electrons from the reducing agent and protons from the aqueous phase to drive the reduction of O2 into H2O2, which is extracted into the aqueous phase during the course of reaction (see picture; DCE = 1,2-dichloroethane). © 2008 Wiley-VCH Verlag GmbH & Co. KGaA.

引用

页码：4675 / 4678

页数：4

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