A novel Cr-CeO2/La2O3nanocomposite electrodeposited in sulphate Cr(III) bath

被引:1
作者
Bikulcius, G. [1 ]
Cesuniene, A. [1 ]
Selskiene, A. [1 ]
Matijosius, T. [1 ]
Pakstas, V [1 ]
Bucinskiene, D. [1 ]
机构
[1] Ctr Phys Sci & Technol FTMC, Dept Electrochem Mat Sci, Sauletekio Av 3, LT-10257 Vilnius, Lithuania
来源
TRANSACTIONS OF THE INSTITUTE OF METAL FINISHING | 2020年 / 98卷 / 04期
关键词
Electrodeposition; Cr (III); CeO2 / La(2)O(3)nanoparticles; nanocomposite; hardness; wear resistance; XRD; friction coefficient; COMPOSITE COATINGS; WEAR BEHAVIOR; NANOCOMPOSITE; MICROSTRUCTURE; KINETICS; COBALT; CEO2;
D O I
10.1080/00202967.2020.1782033
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
For the first time, the Cr-CeO2/ La(2)O(3)composite has been electrochemically deposited in a sulphate Cr (III) bath with an oxalate complexing agent. XRD analysis revealed that incorporation of CeO2/La(2)O(3)particles into the Cr matrix does not change its state and the Cr matrix remains fine-crystalline (crystallites size < 1 nm). The cross-section SEM and EDS analysis confirmed the incorporation of CeO2/La(2)O(3)particles into the Cr matrix. The studies of the mechanical properties of the Cr-CeO2/La(2)O(3)composite have shown that the hardness of the composite increases over that of the Cr deposit due to CeO2/La(2)O(3)particles incorporation, while both the friction coefficient and wear rate decrease. The mechanism of CeO2/La(2)O(3)nanoparticles incorporation into the Cr matrix has been discussed.
引用
收藏
页码:199 / 208
页数:10
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