Tuning a reaction using two-site catalysis and far-from-equilibrium conditions

被引：9

作者：

Lemarchand, A

Jullien, L

机构：

[1] Univ Paris 06, Phys Theor Liquides Lab, CNRS, UMR 7600, F-75252 Paris 05, France

[2] Ecole Normale Super, Dept Chim, CNRS, UMR 8640, F-75321 Paris 05, France

来源：

PHYSICAL CHEMISTRY CHEMICAL PHYSICS | 2004年 / 6卷 / 02期

关键词：

D O I：

10.1039/b306678a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

We show that a given kinetic mechanism, appropriate for describing the evolution of concentrations in a two-site catalysis, exhibits various properties when maintaining the system far from equilibrium and varying the order of magnitude of the rate constants: tuning of reaction yield, autocatalysis and kinetic proofreading are obtained. The model, involving molecules with two coupled reactive sites, gives some hints to design simple artificial systems possessing complex properties of living systems.

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页码：398 / 405

页数：8

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