The generation of a novel polyoxometalate-based 3D framework following picolinate-chelation of tungsten and potassium centres

被引：24

作者：

Ritchie, Chris ^{[1
]}

Miller, Chloe E. ^{[1
]}

Boskovic, Colette ^{[1
]}

机构：

[1] Univ Melbourne, Sch Chem, Melbourne, Vic 3010, Australia

来源：

DALTON TRANSACTIONS | 2011年 / 40卷 / 45期

基金：

澳大利亚研究理事会;

关键词：

ORGANIC FRAMEWORKS; COMPLEXES; BINUCLEAR; CHEMISTRY; DESIGN;

D O I：

10.1039/c1dt10866b

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new polyoxometalate-based 3D framework K5Na-[K-2{Dy(H2O)(3)}(2){As2W19O68}{WO2(pic)}(2)] (1) (pic = 2-picolinate), composed of picolinate-functionalised dysprosium-containing tungstoarsenates and distorted potassium-picolinate cubane units, has been synthesised from the polyoxometalate precursor [As2W19O67(H2O)](14-).

引用

页码：12037 / 12039

页数：3

共 29 条

[1] Thermally stable potassium N-heterocyclic carbene complexes with alkoxide ligands, and a polymeric crystal structure with distorted, bridging carbenes [J].

Arnold, PL ;

Rodden, M ;

Wilson, C .

CHEMICAL COMMUNICATIONS, 2005, (13) :1743-1745

[2]

Bradley D. C, 2001, ALKOXO ARYLOXO DERIV

[3] Solid state coordination chemistry: One-, two-, and three-dimensional materials constructed from molybdophosphonate subunits linked through binuclear copper tetra-2-pyridylpyrazine groups [J].

Burkholder, E ;

Golub, V ;

O'Connor, CJ ;

Zubieta, J .

INORGANIC CHEMISTRY, 2003, 42 (21) :6729-6740

[4] Hybrid Organic-Inorganic Polyoxometalate Compounds: From Structural Diversity to Applications [J].

Dolbecq, Anne ;

Dumas, Eddy ;

Mayer, Cedric R. ;

Mialane, Pierre .

CHEMICAL REVIEWS, 2010, 110 (10) :6009-6048

[5] Radical Cyclizations Terminated by Ir-Catalyzed Hydrogen Atom Transfer [J].

Gansaeuer, Andreas ;

Otte, Matthias ;

Shi, Lei .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2011, 133 (03) :416-417

[6] A coordination network that catalyzes O2-based oxidations [J].

Han, Jong Woo ;

Hill, Craig L. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2007, 129 (49) :15094-+

[7]

Kortz U, 2001, ANGEW CHEM INT EDIT, V40, P3384, DOI 10.1002/1521-3773(20010917)40:18<3384::AID-ANIE3384>3.0.CO

[8]

2-O

[9] Inorganic-organic hybrid compounds based on octamolybdates and metal-organic fragments with flexible multidentate ligand: syntheses, structures and characterization [J].

Liu, Hai-Yan ;

Wu, Hua ;

Ma, Jian-Fang ;

Liu, Ying-Ying ;

Yang, Jin ;

Ma, Ji-Cheng .

DALTON TRANSACTIONS, 2011, 40 (03) :602-613

[10] Polyoxometalate clusters, nanostructures and materials: From self assembly to designer materials and devices [J].

Long, De-Liang ;

Burkholder, Eric ;

Cronin, Leroy .

CHEMICAL SOCIETY REVIEWS, 2007, 36 (01) :105-121

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