Bridging the Gap between Industrial and Well-Defined Supported Catalysts

被引：196

作者：

Coperet, Christophe ^{[1
]}

Allouche, Florian ^{[1
]}

Chan, Ka Wing ^{[1
]}

Conley, Matthew P. ^{[1
,2
]}

Delley, Murielle F. ^{[1
]}

Fedorov, Alexey ^{[1
]}

Moroz, Ilia B. ^{[1
]}

Mougel, Victor ^{[1
,3
]}

Pucino, Margherita ^{[1
]}

Searles, Keith ^{[1
]}

Yamamoto, Keishi ^{[1
]}

Zhizhko, Pavel A. ^{[1
,4
]}

机构：

[1] Swiss Fed Inst Technol, Dept Chem & Appl Biosci, Vladimir Prelog Weg 1-5, CH-8093 Zurich, Switzerland

[2] Univ Calif Riverside, Dept Chem, 501 Big Springs Rd, Riverside, CA 92521 USA

[3] Univ Paris 06, Coll France, CNRS, Lab Chim Proc Biol,UMR 8229, 11 Pl Marcelin Berthelot, F-75005 Paris, France

[4] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Vavilov St 28, Moscow 119991, Russia

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2018年 / 57卷 / 22期

关键词：

heterogeneous catalysis; industrial processes; isolated active centers; olefins; surfaceorganome-tallic chemistry; SURFACE ORGANOMETALLIC CHEMISTRY; OLEFIN-METATHESIS CATALYSTS; PHILLIPS POLYMERIZATION CATALYST; ZIEGLER-NATTA POLYMERIZATION; TUNGSTEN-OXO-ALKYLIDENE; X-RAY-ABSORPTION; SELECTIVE ETHYLENE TRIMERIZATION; SITE HETEROGENEOUS CATALYSTS; MAIN-GROUP ELEMENTS; H BOND ACTIVATION;

D O I：

10.1002/anie.201702387

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Many industrial catalysts contain isolated metal sites on the surface of oxide supports. Although such catalysts have been used in a broad range of processes for more than 40 years, there is often a very limited understanding about the structure of the catalytically active sites. This Review discusses how surface organometallic chemistry (SOMC) engineers surface sites with well-defined structures and provides insight into the nature of the active sites of industrial catalysts; the Review focuses in particular on olefin production and conversion processes.

引用

页码：6398 / 6440

页数：43

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