pulsed DC discharge;
N2O;
vibrational populations;
D O I:
暂无
中图分类号:
O433 [光谱学];
学科分类号:
0703 ;
070302 ;
摘要:
A new equipment of pulsed DC discharge supersonic molecular beam was set up for producing transient species. The pulsed DC discharge can be used stably under 10 kV. In data collection using software, it can be utilized as gated integrators and averagers. Using this equipment, the processes of N2O discharge were studied. The emission spectra of N2O+ ((A) over tilde (2) Sigma(+) - (X) over tilde (2) Pi(i)) were obtained. From the intensity of vibrational spectra, the vibrational populations of the N2O+ ((A) over tilde (2) Sigma(+)) states were calculated. Compared with other results, (A) over tilde states of N2O+ depart even more from a Boltzmann distribution.