Influence of self-doped poly(aniline-co-4-amino-3-hydroxy-naphthalene-1-sulfonic acid) on corrosion inhibition behaviour of iron in acidic medium

This paper presents the corrosion inhibition performance of soluble self-doped copolymers of aniline and 4-amino-3-hydroxy-naphthalene-1-sulfonic acid synthesized by chemical oxidative polymerization method. The corrosion inhibition behaviour of the copolymers in 1.0 M HCl has been evaluated using Tafel Extrapolation method and electrochemical impedance spectroscopy (EIS) which was also used to propose the mechanism besides surface morphology. The results showed that the copolymer film exhibited the significant shifting in the corrosion potential and greater charge transfer resistance. The corrosion inhibition efficiency was found to increase from 50% to 90% by increasing the concentration of copolymer from 10 to 70 mg/l in HCl medium. Moreover, the copolymer showed the larger degree of surface coverage onto the iron surface, reflecting the higher inhibition for corrosion of the iron in highly acidic medium. (C) 2011 Elsevier B.V. All rights reserved.