Thiophene-derivatized Pybox and its highly luminescent lanthanide ion complexes

被引：78

作者：

De Bettencourt-Dias, Ana ^{[1
]}

Viswanathan, Subha ^{[1
]}

Rollett, Alexandra ^{[1
,2
]}

机构：

[1] Univ Nevada, Dept Chem, Reno, NV 89557 USA

[2] Syracuse Univ, AR REU Res, Syracuse, NY USA

来源：

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY | 2007年 / 129卷 / 50期

关键词：

D O I：

10.1021/ja076485+

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A new complex of 4-thiophen-3-yl-pyridine-2,6-bis(oxazoline) with Eu(III) triflate has been isolated. This complex and its Tb(III) analogue are luminescent in the solid state. The complexes dissolve with partial retention of the solid-state structure in acetonitrile to yield highly luminescent solutions with quantum yields of 76.2 and 58.6% for red and green emission, respectively.

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页码：15436 / +

页数：3

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