New 1,4,7-triazacyclononane-based functional analogues of the Fe/Cu active site of cytochrome c oxidase:: structure, spectroscopy and electrocatalytic reduction of oxygen

被引：39

作者：

Collman, JP ^{[1
]}

Schwenninger, R ^{[1
]}

Rapta, M ^{[1
]}

Bröring, M ^{[1
]}

Fu, L ^{[1
]}

机构：

[1] Stanford Univ, Dept Chem, Stanford, CA 94305 USA

来源：

CHEMICAL COMMUNICATIONS | 1999年 / 02期

关键词：

D O I：

10.1039/a807598k

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Two new covalently linked functional model compounds for the Fe-a3/Cu-B active sites of heme-copper oxidases have been prepared and characterized by novel synthetic methodologies; the X-ray structure of the Zn form and the electrocatalytic reduction of Oz by the Fe/Cu forms are reported.

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页码：137 / 138

页数：2

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