Analysis of pesticide residues using the Quick Easy Cheap Effective Rugged and Safe (QuEChERS) pesticide multiresidue method in traditional Chinese medicine by gas chromatography with electron capture detection

被引:74
作者
Xu, Rong [1 ]
Wu, Jianwei [1 ,2 ]
Liu, Yougang [3 ]
Zhao, Runhuai [2 ]
Chen, Bo [2 ]
Yang, Meihua [1 ]
Chen, Jun [1 ]
机构
[1] Chinese Acad Med Sci, Peking Union Med Coll, Inst Med Plant Dev, Beijing 100193, Peoples R China
[2] China Natl Grp Corp Tradit & Herbal Med, Technol Dev Ctr, Beijing 102600, Peoples R China
[3] Tianjin Univ Tradit Chinese Med, Tianjin 300193, Peoples R China
关键词
QuEChERS; Organochlorine pesticides; Gas chromatography; Traditional Chinese medicines; SOLID-PHASE EXTRACTION; ORGANOCHLORINE PESTICIDES; SAMPLES; FOOD;
D O I
10.1016/j.chemosphere.2011.06.013
中图分类号
X [环境科学、安全科学];
学科分类号
08 ; 0830 ;
摘要
The Quick Easy Cheap Effective Rugged and Safe multiresidue method (QuEChERS) has been validated for the extraction of 15 organochlorine pesticides (OCPs) in completely different matrices of traditional Chinese medicine (TCM). The method employed a rapid, simple and cost-effective procedure. The spiking levels for the recovery experiments were 0.1, 0.5 and 2.0 mg kg(-1). Mean recoveries mostly ranged between 76.0% and 114.0% (96.0% on average), and relative standard deviations (RSD) were generally below 10% (4.72% on average). Based on these results, the methodology has been proven to be highly efficient and robust and thus suitable for monitoring the MRL compliance of a wide range of commodity. The contamination status of 15 OCPs on 80 different TCMs marketed in China, and a total of 400 samples were also performed using a previously validated method. 15 OCPs were benzene hexachloride (BHC, including alpha-BHC, beta-BHC, gamma-BHC, delta-BHC), hexachlorobenzene, heptachlor, heptachlor epoxide, aldrin, p, p'-DDE, p, p'-DDD, o, p'-DDT, p, p'-DDT, mirex, endrin, dieldrin. This study indicates that the proposed method is useful for analyzing OCPs in TCM. Crown Copyright (C) 2011 Published by Elsevier Ltd. All rights reserved.
引用
收藏
页码:908 / 912
页数:5
相关论文
共 50 条
[41]   Determination of pesticides in dried minor tropical fruits from Colombia using the Quick, Easy, Cheap, Effective, Rugged, and Safe method-gas chromatography-tandem mass spectrometry [J].
Varela-Martinez, Diana Angelica ;
Gonzalez-Curbelo, Miguel Angel ;
Gonzalez-Salamo, Javier ;
Hernandez-Borges, Javier .
JOURNAL OF SEPARATION SCIENCE, 2020, 43 (05) :929-935
[42]   Determination of Herbicide Propisochlor in Soil, Water and Rice by Quick, Easy, Cheap, Effective, Rugged and Safe (QuEChERS) Method Using by UPLC-ESI-MS/MS [J].
Wu, Xiaohu ;
Xu, Jun ;
Liu, Xingang ;
Dong, Fengshou ;
Wu, Yanbing ;
Zhang, Ying ;
Zheng, Yongquan .
BULLETIN OF THE KOREAN CHEMICAL SOCIETY, 2013, 34 (03) :917-921
[43]   Comparing a two-dimensional liquid chromatography with a quick, easy, cheap, effective, rugged, and safe protocol-based liquid chromatography method for matrix removal in pesticide analysis using time-of-flight mass spectrometry [J].
Muehlwald, Sandra ;
Meyburg, Nina ;
Rohn, Sascha ;
Buchner, Nadja .
JOURNAL OF CHROMATOGRAPHY A, 2020, 1623
[44]   Determination of cyromazine and melamine in chicken eggs using quick, easy, cheap, effective, rugged and safe (QuEChERS) extraction coupled with liquid chromatography-tandem mass spectrometry [J].
Wang, Pei-Cheng ;
Lee, Ren-Jye ;
Chen, Chung-Yu ;
Chou, Chi-Chung ;
Lee, Maw-Rong .
ANALYTICA CHIMICA ACTA, 2012, 752 :78-86
[45]   A throughput method using the quick easy cheap effective rugged safe method for the quantification of ibuprofen and its main metabolites in soils [J].
Cristina Delerue-Matos, Paula Paiga .
JOURNAL OF SEPARATION SCIENCE, 2016, 39 (17) :3436-3444
[46]   Trace analysis of multi-class pesticide residues in Chinese medicinal health wines using gas chromatography with electron capture detection [J].
Kong, Wei-Jun ;
Liu, Qiu-Tao ;
Kong, Dan-Dan ;
Liu, Qian-Zhen ;
Ma, Xin-Ping ;
Yang, Mei-Hua .
SCIENTIFIC REPORTS, 2016, 6
[47]   Development of a green miniaturized quick, easy, cheap, effective, rugged, and safe approach in tandem with temperature-assisted solidification of floating menthol droplet for analysis of multiclass pesticide residues in milk [J].
Sereshti, Hassan ;
Jazani, Saba Semnani ;
Nouri, Nina ;
AliAbadi, Mohammad Hossein Shojaee .
JOURNAL OF SEPARATION SCIENCE, 2022, 45 (05) :1106-1115
[48]   Simplified multiresidue method for determination of pesticide residues in lettuce by gas chromatography with nitrogen–phosphorus detection [J].
José Fenoll ;
Pilar Hellín ;
Josefa López ;
Alberto González ;
Pilar Flores .
Analytical and Bioanalytical Chemistry, 2007, 389 :643-651
[49]   Determination of benzothiazoles, benzotriazoles and benzenesulfonamides in seafood using quick, easy, cheap, effective, rugged and safe extraction followed by gas chromatography- tandem mass spectrometry: Method development and risk assessment [J].
Castro, Oscar ;
Borrull, Silvia ;
Pocurull, Eva ;
Borrull, Francesc .
JOURNAL OF CHROMATOGRAPHY A, 2023, 1691
[50]   Development and Validation of a Quick Easy Cheap Effective Rugged and Safe-based Multi-residues Analysis Method for Persimmon, Grape and Pear using Liquid Chromatography-tandem Mass Spectrometry [J].
Min, Zaw Win ;
Lee, Ju Young ;
Son, Kyung-Ae ;
Im, Geon-Jae ;
Hong, Su-Myeong .
JOURNAL OF THE KOREAN SOCIETY FOR APPLIED BIOLOGICAL CHEMISTRY, 2011, 54 (05) :771-777