On the compensation effect at the form of the differential conversion function

被引：15
作者：
Budrugeac, P
Segal, E
机构：
[1] EUROTEST SA, Bucharest 73204, Romania
[2] Univ Bucharest, Fac Chem, Dept Phys Chem, Bucharest, Romania
来源：
JOURNAL OF THERMAL ANALYSIS AND CALORIMETRY | 1998年 / 53卷 / 01期
关键词：
compensation effect; non-isothermal kinetic parameters;
D O I：
10.1023/A:1010160930434
中图分类号：
O414.1 [热力学];
学科分类号：
摘要：
From the general form of the rate equation under non-isothermal conditions, some relationships showing the existence of a compensation effect due to the change of the analytical form of the differential conversion function were derived. These relationships were checked for some simulated TG curves, as well as thermogravimetric data corresponding to the degradation of some polymers and to the decomposition of calcium carbonate.
引用
收藏
页码：269 / 283
页数：15
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