Visible-light-promoted and photocatalyst-free trifluoromethylation of enamides

被引：64
作者：
Wang, Hao
Cheng, Yuanzheng
Yu, Shouyun [1 ]
机构：
[1] State Key Lab Analyt Chem Life Sci, Nanjing 210093, Jiangsu, Peoples R China
来源：
SCIENCE CHINA-CHEMISTRY | 2016年 / 59卷 / 02期
基金：
中国国家自然科学基金;
关键词：
enamide; photochemistry; visible light; trifluoromethylation; radical; CATALYZED ENANTIOSELECTIVE HYDROGENATION; TRANSITION-METAL-COMPLEXES; PHOTOREDOX CATALYSIS; ORGANIC-SYNTHESIS; NUCLEOPHILES; CHEMISTRY; ALDEHYDES; FLUORINE; AMINO; ACID;
D O I：
10.1007/s11426-015-5528-1
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient and practical method is developed for the trifluoromethylation of enamides using Umemoto's reagent as the trifluoromethylating reagent. These reactions proceeded under visible light irradiation without any photocatalyst at room temperature in good chemical yields.
引用
收藏
页码：195 / 198
页数：4
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