Calcium vanadate sub-microfibers as highly reversible host cathode material for aqueous zinc-ion batteries

被引：127

作者：

Liu, Xu ^{[1
,2
]}

Zhang, Huang ^{[1
,2
]}

Geiger, Dorin ^{[3
]}

Han, Jin ^{[1
,2
]}

Varzi, Alberto ^{[1
,2
]}

Kaiser, Ute ^{[3
]}

Moretti, Arianna ^{[1
,2
]}

Passerini, Stefano ^{[1
,2
]}

机构：

[1] HIU, Electrochem 1, D-89081 Ulm, Germany

[2] KIT, D-76021 Karlsruhe, Germany

[3] Ulm Univ, Electron Microscopy Grp Mat Sci, Cent Facil Electron Microscopy, Albert Einstein Allee 11, D-89081 Ulm, Germany

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 16期

关键词：

STORAGE;

D O I：

10.1039/c8cc07243d

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

For the first time, CaV6O16 center dot 3H(2)O (CVO), synthesized via a highly efficient and fast microwave reaction, is used as a cathode material for aqueous zinc-ion batteries. Ex situ X-ray diffraction confirms the structure of this material to be stable upon reversible Zn2+ intercalation, due to its large interlayer distance (8.08 angstrom). The pillaring effect of calcium makes the as-prepared CVO an excellent Zn2+ cation host.

引用

页码：2265 / 2268

页数：4

共 32 条

[1] Electrochemical Zinc Intercalation in Lithium Vanadium Oxide: A High-Capacity Zinc-Ion Battery Cathode [J].

Alfaruqi, Muhammad H. ;

Mathew, Vinod ;

Song, Jinju ;

Kim, Sungjin ;

Islam, Saiful ;

Pham, Duong Tung ;

Jo, Jeonggeun ;

Kim, Seokhun ;

Baboo, Joseph Paul ;

Xiu, Zhiliang ;

Lee, Kug-Seung ;

Sun, Yang-Kook ;

Kim, Jaekook .

CHEMISTRY OF MATERIALS, 2017, 29 (04) :1684-1694

[2] Pilotaxitic Na1.1V3O7.9 nanoribbons/graphene as high-performance sodium ion battery and aqueous zinc ion battery cathode [J].

Cai, Yangsheng ;

Liu, Fei ;

Luo, Zhigao ;

Fang, Guozhao ;

Zhou, Jiang ;

Pan, Anqiang ;

Liang, Shuquan .

ENERGY STORAGE MATERIALS, 2018, 13 :168-174

[3] Metahewettite, Ca(V5+6O16)(H2O)3, from Hodzha-Rushnai-Mazar, southern Kirgizia: occurrence and crystal structure [J].

Cooper, Mark A. ;

Hawthorne, Frank C. ;

Karpenko, Vladimir Y. ;

Pautov, Leonid A. ;

Agakhanov, Atali A. .

JOURNAL OF GEOSCIENCES, 2014, 59 (02) :159-168

[4] Ultrafast Zn2+ Intercalation and Deintercalation in Vanadium Dioxide [J].

Ding, Junwei ;

Du, Zhiguo ;

Gu, Linqing ;

Li, Bin ;

Wang, Lizhen ;

Wang, Shiwen ;

Gong, Yongji ;

Yang, Shubin .

ADVANCED MATERIALS, 2018, 30 (26)

[5] Sodium Ion Stabilized Vanadium Oxide Nanowire Cathode for High-Performance Zinc-Ion Batteries [J].

He, Pan ;

Zhang, Guobin ;

Liao, Xiaobin ;

Yan, Mengyu ;

Xu, Xu ;

An, Qinyou ;

Liu, Jun ;

Mai, Liqiang .

ADVANCED ENERGY MATERIALS, 2018, 8 (10)

[6] Highly Durable Na2V6O16•1.63H2O Nanowire Cathode for Aqueous Zinc-Ion Battery [J].

Hu, Ping ;

Zhu, Ting ;

Wang, Xuanpeng ;

Wei, Xiujuan ;

Yan, Mengyu ;

Li, Jiantao ;

Luo, Wen ;

Yang, Wei ;

Zhang, Wencui ;

Zhou, Liang ;

Zhou, Zhiqiang ;

Mai, Liqiang .

NANO LETTERS, 2018, 18 (03) :1758-1763

[7] Hydrothermal growth of single-crystal CaV6O16•3H2O nanoribbons [J].

Kong, LF ;

Shao, MW ;

Xie, Q ;

Liu, HW ;

Qian, YT .

JOURNAL OF CRYSTAL GROWTH, 2004, 260 (3-4) :435-439

[8]

Kundu D, 2016, NAT ENERGY, V1, DOI [10.1038/NENERGY.2016.119, 10.1038/nenergy.2016.119]

[9] Towards polyvalent ion batteries: A zinc-ion battery based on NASICON structured Na3V2(PO4)3 [J].

Li, Guolong ;

Yang, Ze ;

Jiang, Yan ;

Jin, Chuanhong ;

Huang, Wei ;

Ding, Xuli ;

Huang, Yunhui .

NANO ENERGY, 2016, 25 :211-217

[10] Thermal Hydrolysis Synthesis and Characterization of Monoclinic Metahewettite CaV6O16•3H2O [J].

Li Lanijie ;

Zheng Shili ;

Wang Shaona ;

Du Hao ;

Zhang Yi .

JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY-MATERIALS SCIENCE EDITION, 2014, 29 (03) :433-440

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