Accelerated Heck reaction using ortho-palladated complex with controlled microwave heating

被引：24

作者：

Hajipour, Abdol R. ^{[1
,2
]}

Karami, Kazem ^{[1
]}

Pirisedigh, Azadeh ^{[1
]}

机构：

[1] Isfahan Univ Technol, Dept Chem, Pharmaceut Res Lab, Esfahan 84156, Iran

[2] Univ Wisconsin, Sch Med, Dept Pharmacol, Madison, WI 53706 USA

来源：

APPLIED ORGANOMETALLIC CHEMISTRY | 2009年 / 23卷 / 12期

关键词：

microwave; heck reaction; ortho-palladate; catalyst; CYCLOPALLADATED COMPLEXES; PALLADIUM CATALYSTS; MOLECULAR-STRUCTURE; PRIMARY AMINES; PALLADACYCLES; EFFICIENT; BOND; FUNCTIONALIZATION; CHEMISTRY; ARYLATION;

D O I：

10.1002/aoc.1556

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

Palladium-catalyzed Heck couplings utilizing [Pd{C6H2(CH2CH2NH2)-(OMe)(2),3,4} (mu-Br)](2) palladacycle catalyst and microwave irradiation lead to formation of different coupling products. This complex is an active and efficient catalyst for the Heck reaction of aryl iodides, bromides and even less reactive chlorides. The cross-coupled products were produced in excellent yields. The reaction time was reduced from hours to minutes and full conversion was achieved under microwave irradiation. Copyright (C) 2009 John Wiley & Sons, Ltd.

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收藏

页码：504 / 511

页数：8

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