Coupling between the photo-excited cyclic π system and the 4f electronic system in a lanthanide single molecule magnet

被引：22
|
作者：
Kizaki, K. [1 ]
Ozawa, H. [1 ]
Kobayashi, T. [1 ]
Matsuoka, R. [1 ,2 ,3 ]
Sakaguchi, Y. [1 ]
Fuyuhiro, A. [1 ]
Fukuda, T. [1 ]
Ishikawa, N. [1 ]
机构：
[1] Osaka Univ, Grad Sch Sci, Dept Chem, Toyonaka, Osaka 5600043, Japan
[2] Univ Tsukuba, Grad Sch Pure & Appl Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan
[3] Univ Tsukuba, Tsukuba Res Ctr Interdisciplinary Mat Sci, 1-1-1 Tennodai, Tsukuba, Ibaraki 3058571, Japan
来源：
CHEMICAL COMMUNICATIONS | 2017年 / 53卷 / 45期
关键词：
EXTENDED HUCKEL CALCULATIONS; LIGAND-FIELD PARAMETERS; SPIN; PORPHYRINS; PHTHALOCYANINE; COMPLEXES; MAGNETIZATION;
D O I：
10.1039/c7cc02960h
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
A new type of electronic interaction which couples two angular momenta, i.e. the angular momentum of a localized 4f system (J) and an orbital angular momentum generated in a cyclic pi conjugated system by irradiation with a circularly-polarized light, has been identified in a lanthanide single molecule magnet.
引用
收藏
页码：6168 / 6171
页数：4
相关论文
共 36 条
  • [1] Antiparallel Coupling between a 4f System and a Photoexcited Cyclic π System in a Dysprosium(III) Monoporphyrinato Complex
    Santria, Anas
    Ishikawa, Naoto
    INORGANIC CHEMISTRY, 2021, 60 (18) : 14418 - 14425
  • [2] Understanding Single-Molecule Magnet properties of lanthanide complexes from 4f orbital splitting
    Gil, Yolimar
    Aravena, Daniel
    DALTON TRANSACTIONS, 2024, 53 (05) : 2207 - 2217
  • [3] Single-molecule magnet behavior enhanced by magnetic coupling between 4f and 3d spins
    Okazawa, Atsushi
    Nojiri, Hiroyuki
    Ishida, Takayuki
    Kojima, Norimichi
    POLYHEDRON, 2011, 30 (18) : 3140 - 3144
  • [4] Uncommon lanthanide ions in purely 4f Single Molecule Magnets
    Pointillart, Fabrice
    Cador, Olivier
    Le Guennic, Boris
    Ouahab, Lahcene
    COORDINATION CHEMISTRY REVIEWS, 2017, 346 : 150 - 175
  • [5] Spectroscopic Investigation of Interaction between the 4f Electronic System and the Photoexcited Cyclic π System in Terbium(III) Monoporphyrinato Complex
    Santria, Anas
    Ishikawa, Naoto
    INORGANIC CHEMISTRY, 2020, 59 (19) : 14326 - 14336
  • [6] Cyclic single-molecule magnet in heterospin system
    Yoshihara, Daisuke
    Karasawa, Satoru
    Koga, Noboru
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2008, 130 (32) : 10460 - +
  • [7] Coupling of magnetic orders in a 4f metal/oxide system
    Averyanov, Dmitry V.
    Tokmachev, Andrey M.
    Parfenov, Oleg E.
    Karateev, Igor A.
    Taldenkov, Alexander N.
    Storchak, Vyacheslav G.
    JOURNAL OF MATERIALS CHEMISTRY C, 2018, 6 (37) : 9950 - 9957
  • [8] An Organometallic Building Block Approach To Produce a Multidecker 4f Single-Molecule Magnet
    Le Roy, Jennifer J.
    Jeletic, Matthew
    Gorelsky, Serge I.
    Korobkov, Ilia
    Ungur, Liviu
    Chibotaru, Liviu F.
    Murugesu, Muralee
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2013, 135 (09) : 3502 - 3510
  • [9] Electronic coupling between photo-excited stacked bases in DNA and RNA strands with emphasis on the bright states initially populated
    Nielsen, Lisbeth Munksgaard
    Hoffmann, Soren Vronning
    Nielsen, Steen Brondsted
    PHOTOCHEMICAL & PHOTOBIOLOGICAL SCIENCES, 2013, 12 (08) : 1273 - 1285
  • [10] Electronic coupling between photo-excited stacked bases in DNA and RNA strands with emphasis on the bright states initially populated
    Lisbeth Munksgaard Nielsen
    Søren Vrønning Hoffmann
    Steen Brøndsted Nielsen
    Photochemical & Photobiological Sciences, 2013, 12 : 1273 - 1285
1234