Superhydrophobic organosilicon-based coating system by a novel ultravoiletcurable method

被引:16
作者
Liu, Baojiang [1 ,2 ,3 ]
Tian, Taizhou [2 ]
Yao, Jinlong [3 ]
Huang, Changgen [3 ]
Tang, Wenjun [3 ]
Xiang, Zhonglin [3 ]
Xu, Xiaojun [3 ]
Min, Jie [2 ]
机构
[1] Donghua Univ, Minist Educ, Key Lab High Performance Fibers & Prod, Shanghai, Peoples R China
[2] Donghua Univ, Coll Chem Chem Engn & Biotechnol, Shanghai, Peoples R China
[3] Jiangsu Lianfa Text Co Ltd, Key Lab Ecodyeing & Finishing Text Jiangsu Prov, Nantong, Jiangsu, Peoples R China
关键词
Cotton fabric; organosilicon-based; superhydrophobicity; SILICA NANOPARTICLES; SURFACE; COTTON; FILMS; WETTABILITY; ROUTE; LOTUS;
D O I
10.1177/1847980417702795
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A robust superhydrophobic organosilica sol-gel-based coating on a cotton fabric substrate was successfully fabricated via a cost-effective one-step method. The coating was prepared by modification of silica nanoparticles with siloxane having long alkyl chain that allow to reduce surface energy. The coating on cotton fabric exhibited water contact angle of 151.6 degrees. The surface morphology was evaluated by scanning electron microscopy, and surface chemical composition was measured with X-ray photoelectron spectroscopy. Results showed the enhanced superhydrophobicity that was attributed to the synergistic effect of roughness created by the random distribution of silica nanoparticles and the low surface energy imparted of long-chain alkane siloxane. In addition, the coating also showed excellent durability against washing treatments. Even after washed for 30 times, the specimen still had a water contact angle of 130 degrees, indicating an obvious water-repellent property. With this outstanding property, the robust superhydrophobic coating exhibited a prospective application in textiles and plastics.
引用
收藏
页数:10
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共 37 条
[21]   Superhydrophobic surfaces and emerging applications: Non-adhesion, energy, green engineering [J].
Nosonovsky, Michael ;
Bhushan, Bharat .
CURRENT OPINION IN COLLOID & INTERFACE SCIENCE, 2009, 14 (04) :270-280
[22]   Surface phenomena -: Contact time of a bouncing drop [J].
Richard, D ;
Clanet, C ;
Quéré, D .
NATURE, 2002, 417 (6891) :811-811
[23]   Selective etching of semicrystalline polymers:: CF4 gas plasma treatment of poly(ethylene) [J].
Riekerink, MBO ;
Terlingen, JGA ;
Engbers, GHM ;
Feijen, J .
LANGMUIR, 1999, 15 (14) :4847-4856
[24]   Progess in superhydrophobic surface development [J].
Roach, Paul ;
Shirtcliffe, Neil J. ;
Newton, Michael I. .
SOFT MATTER, 2008, 4 (02) :224-240
[25]   Controllable water permeation on a poly(N-isopropylacrylamide)-modified nanostructured copper mesh film [J].
Song, Wenlong ;
Xia, Fan ;
Bai, Yubai ;
Liu, Fengqi ;
Sun, Taolei ;
Jiang, Lei .
LANGMUIR, 2007, 23 (01) :327-331
[26]   Bioinspired surfaces with special wettability [J].
Sun, TL ;
Feng, L ;
Gao, XF ;
Jiang, L .
ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (08) :644-652
[27]   Formation of superhydrophobic alumina coating films with high transparency on polymer substrates by the sol-gel method [J].
Tadanaga, K ;
Kitamuro, K ;
Matsuda, A ;
Minami, T .
JOURNAL OF SOL-GEL SCIENCE AND TECHNOLOGY, 2003, 26 (1-3) :705-708
[28]   One-step coating of fluoro-containing silica nanoparticles for universal generation of surface superhydrophobicity [J].
Wang, Hongxia ;
Fang, Jian ;
Cheng, Tong ;
Ding, Jie ;
Qu, Liangti ;
Dai, Liming ;
Wang, Xungai ;
Lin, Tong .
CHEMICAL COMMUNICATIONS, 2008, (07) :877-879
[29]   Surface structure determines dynamic wetting [J].
Wang, Jiayu ;
Minh Do-Quang ;
Cannon, James J. ;
Yue, Feng ;
Suzuki, Yuji ;
Amberg, Gustav ;
Shiomi, Junichiro .
SCIENTIFIC REPORTS, 2015, 5
[30]   A general route to transform normal hydrophilic cloths into superhydrophobic surfaces [J].
Wang, Tie ;
Hu, Xiaoge ;
Dong, Shaojun .
CHEMICAL COMMUNICATIONS, 2007, (18) :1849-1851