Hydrothermal Synthesis, Crystal Structure and Thermal Stability of two 3d-4f Heterometallic Coordination Polymers

被引：5

作者：

Huang, Chun-De ^{[1
]}

Qiu, Tao-Run ^{[1
]}

Wu, Yi-Yi ^{[1
]}

Mo, Hai-Hong ^{[1
]}

Zeng, Rong-Hua ^{[1
]}

Peng, Guo ^{[1
]}

Wang, Ning ^{[1
]}

Lu, Dong-Sheng ^{[1
]}

Fang, Zhan-Qiang ^{[1
]}

机构：

[1] S China Normal Univ, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

来源：

ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2009年 / 635卷 / 15期

关键词：

Nicotinic acid; Rare earths; Copper; Hydrothermal synthesis; Coordination polymer; LN-AG LN; FRAMEWORKS; ISONICOTINATE; CONSTRUCTION; DESIGN; EU; CHEMISTRY; CLUSTERS; CHANNELS; SERIES;

D O I：

10.1002/zaac.200900304

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Two new 3d-4f heterometallic coordination Polymers, [LnCu(nic)(2)(ox)]center dot 2H(2)O (Ln = Sm(1), Dy (2), ox = oxalate anion, Hnic = nicotinic acid) were synthesized and characterized by elementary analysis, IR spectroscopy and thermogravimetric analysis, as well as single-crystal X-ray diffraction. The two structures exhibit the same unusual 3D microporous heterometallic coordination frameworks with 13.7 % voids occupied by guest water molecules.

引用

页码：2381 / 2384

页数：4

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