A new type of metal porphyrin dissociation reaction

被引：0

作者：

Berezin, BD ^{[1
]}

Shukhto, OV

Berezin, DB

机构：

[1] Russian Acad Sci, Inst Solut Chem, Ivanovo, Russia

[2] Ivanovo State Univ Chem Technol, Ivanovo, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2002年 / 47卷 / 11期

关键词：

D O I：

暂无

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Electronic spectroscopy and chemical kinetics were the tools used to study the dissociation of Mg-tetra(tert-butyl)phthalocyanine in ethanol-acetic acid from 298 to 318 K. The activation energies and entropy changes in the reaction were calculated. The results are discussed in terms of the acidoprotolytic dissociation of the magnesium complex. It was shown that an undissociated acetic acid molecule is the major reactant of the title system. The most likely stoichiometric and activation mechanism of the process is discussed.

引用

页码：1763 / 1768

页数：6

共 15 条

[1] Basolo F., 1967, Mechanisms of Inorganic Reactions, pXi + 701
[2] Berezin B.D., 2002, IZV VYSSH UCHEBN ZAV, V45, P5
[3] BEREZIN BD, 1991, TEOR EKSP KHIM, V27, P270
[4] BEREZIN BD, 1989, ZH FIZ KHIM+, V63, P3166
[5] BEREZIN BD, 1987, PORPHYRINS SPECTROSC, P182
[6] BEREZIN BD, 1992, KORDINATSIONNAYA KHI
[7] BEREZIN BD, 1988, METALLOPORFIRINY
[8] DESSY R, 1960, J AM CHEM SOC, V82, P682
[9] CLEAVAGE OF CARBON-METAL BONDS
DESSY, RE
KIM, JY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1961, 83 (05) : 1167 - &
[10] THE MECHANISM OF THE REACTION OF SOME DIALKYL AND DIARYL MERCURY COMPOUNDS WITH HYDROGEN CHLORIDE
DESSY, RE
REYNOLDS, GF
KIM, JY
[J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1959, 81 (11) : 2683 - 2688

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