Sequential elimination-cyclopropanation reactions promoted by samarium:: Highly diastereoselective synthesis of cyclopropylamides

被引：17
作者：
Concellón, JM [1 ]
Rodríguez-Solla, H [1 ]
Llavona, R [1 ]
机构：
[1] Univ Oviedo, Dept Quim Organ & Inorgan, E-33071 Oviedo, Spain
来源：
JOURNAL OF ORGANIC CHEMISTRY | 2003年 / 68卷 / 03期
关键词：
D O I：
10.1021/jo0262098
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
trans-Cyclopropanamides were obtained, in high yield, from 2-chloro-3-hydroxyamides by a sequenced elimination-cyclopropanation process promoted by Samarium/diiodomethane or Samarium diiodide and Samarium/diiodomethane.
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页码：1132 / 1133
页数：2
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