Hydroxyl Radicals Attack Metallic Gold

被引：82

作者：

Nowicka, Anna Maria ^{[1
]}

Hasse, Ulrich ^{[2
]}

Hermes, Michael ^{[2
]}

Scholz, Fritz ^{[2
]}

机构：

[1] Univ Warsaw, Dept Chem, PL-02093 Warsaw, Poland

[2] Ernst Moritz Arndt Univ Greifswald, Inst Biochem, D-17487 Greifswald, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2010年 / 49卷 / 06期

关键词：

electrochemistry; Fenton's reagent; gold; radicals; voltammetry; ELECTROCHEMICAL DETECTION; ULTRAVIOLET OZONE; MICROELECTRODES; MEDICINE;

D O I：

10.1002/anie.200906358

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

(Figure Presented) Cold service: The asperities on a polished gold surface are quickly dissolved by the OH radicals of Fenton's reagent. The dissolution of Au is rapid at the beginning of the reaction and is negligible when the asperities have been dissolved. Although the OH radicals also oxidize the smooth parts of the Au surface, they do not dissolve them, but form a stable oxide monolayer. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA.

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页码：1061 / 1063

页数：3

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