Hydrothermal synthesis and crystal structure of a new two-dimensional zinc citrate complex

被引：36

作者：

Che, P ^{[1
]}

Fang, DQ ^{[1
]}

Zhang, DP ^{[1
]}

Feng, J ^{[1
]}

Wang, JP ^{[1
]}

Hu, NH ^{[1
]}

Meng, J ^{[1
]}

机构：

[1] Chinese Acad Sci, Changchun Inst Appl Chem, Key Lab Rare Earth Chem & Phys, Changchun 130022, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2005年 / 58卷 / 17期

基金：

中国国家自然科学基金;

关键词：

zinc citrate; crystal structure; hydrothermal synthesis;

D O I：

10.1080/00958970500244112

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

new two-dimensional compound C12H14O16Zn3 ( 1), containing seven-coordinate zinc atoms was prepared by the hydrothermal technique. The compound obtained was characterized by TG-DTA, single crystal X-ray diffraction, elemental analysis and FT-IR analysis. Single-crystal X-ray diffraction analysis shows that compound 1 crystallizes with monoclinic symmetry in the space group P2(1)/c, a = 6.1552(13) angstrom, b = 14.546(3) angstrom, c = 9.581 angstrom, beta = 102.66(2)degrees, V = 836.9(4) angstrom(3), Z = 2, R1 = 0.0311, wR2 = 0.0830.

引用

收藏

页码：1581 / 1588

页数：8

相关论文

共 13 条

[1] Zinc takes the center stage:: its paradoxical role in Alzheimer's disease [J].

Cuajungco, MP ;

Fagét, KY .

BRAIN RESEARCH REVIEWS, 2003, 41 (01) :44-56

[2] SYNTHESIS, STRUCTURAL CHARACTERIZATION, AND PROPERTIES OF NEW SINGLE AND DOUBLE CUBANES CONTAINING THE MOFE3S4 STRUCTURAL UNIT AND MOLYBDENUM-BOUND POLYCARBOXYLATE LIGANDS - CLUSTERS WITH A MOLYBDENUM-COORDINATION ENVIRONMENT SIMILAR TO THAT IN THE IRON MOLYBDENUM COFACTOR OF NITROGENASE [J].

DEMADIS, KD ;

COUCOUVANIS, D .

INORGANIC CHEMISTRY, 1995, 34 (02) :436-448

[3] Lead-citrate chemistry. Synthesis, spectroscopic and structural studies of a novel lead(II)-citrate aqueous complex [J].

Kourgiantakis, M ;

Matzapetakis, M ;

Raptopoulou, CP ;

Terzis, A ;

Salifoglou, A .

INORGANICA CHIMICA ACTA, 2000, 297 (1-2) :134-138

[4] Two isomeric lead(II) carboxylate-phosphonates: syntheses, crystal structures and characterizations [J].

Lei, C ;

Mao, JG ;

Sun, YQ .

JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (07) :2449-2455

[5] Copper, iron and zinc in Alzheimer's disease senile plaques [J].

Lovell, MA ;

Robertson, JD ;

Teesdale, WJ ;

Campbell, JL ;

Markesbery, WR .

JOURNAL OF THE NEUROLOGICAL SCIENCES, 1998, 158 (01) :47-52

[6] Synthesis, structural characterization, and solution behavior of the first mononuclear, aqueous aluminum citrate complex [J].

Matzapetakis, M ;

Raptopoulou, CP ;

Terzis, A ;

Lakatos, A ;

Kiss, T ;

Salifoglou, A .

INORGANIC CHEMISTRY, 1999, 38 (04) :618-+

[7] Preparation and characterization of solid state lanthanum-titanium citrate complexes [J].

Milanova, MM ;

Arnaudov, MG ;

Getsova, MM ;

Todorovsky, DS .

JOURNAL OF ALLOYS AND COMPOUNDS, 1998, 264 (1-2) :95-103

[8] Disruption of zinc homeostasis in Alzheimer's disease [J].

Robertson, JD ;

Crafford, AM ;

Markesbery, WR ;

Lovell, MA .

NUCLEAR INSTRUMENTS & METHODS IN PHYSICS RESEARCH SECTION B-BEAM INTERACTIONS WITH MATERIALS AND ATOMS, 2002, 189 :454-458

[9]

Sheldrick G.M., 1997, SHELX

[10] Hydrothermal synthesis and characterization of layered vanadium phosphite:: [HN(C2H4)3N][(VO)2(HPO3)2(OH)(H2O)]•H2O [J].

Shi, Z ;

Zhang, D ;

Li, GH ;

Wang, L ;

Lu, XY ;

Hua, J ;

Feng, SH .

JOURNAL OF SOLID STATE CHEMISTRY, 2003, 172 (02) :464-470