An eco-friendly procedure for the efficient synthesis of dialkyl α-aminophosphonates in aqueous media

被引：68
|
作者：
Sobhani, Sara [1 ]
Safaei, Elham [2 ]
Asadi, Mozaffar [3 ]
Jalili, Fariba [1 ]
机构：
[1] Birjand Univ, Coll Sci, Dept Chem, Birjand 414, Iran
[2] IASBS, Zanjan 45195, Iran
[3] Shiraz Univ, Coll Sci, Dept Chem, Shiraz 71454, Iran
来源：
JOURNAL OF ORGANOMETALLIC CHEMISTRY | 2008年 / 693卷 / 21-22期
关键词：
alpha-aminophosphonates; aldehydes; amines; aqueous media;
D O I：
10.1016/j.jorganchem.2008.07.037
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A new, convenient and high yielding procedure for the preparation of diethyl alpha-aminophosphonates in water by one-pot reaction of aldehydes, amines, tri/dialkyl phosphites in the presence of a low catalytic amount of [Cu(3,4-tmtppa)](MeSO(4))(4) (0.16 mol%) as a highly stable and re-usable catalyst is described. (C) 2008 Elsevier B.V. All rights reserved.
引用
收藏
页码：3313 / 3317
页数：5
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