Ditopic Ion Transport Systems: Anion-p Interactions and Halogen Bonds at Work

被引：192
|
作者：
Jentzsch, Andreas Vargas [1 ]
Emery, Daniel [1 ]
Mareda, Jiri [1 ]
Metrangolo, Pierangelo [2 ,3 ]
Resnati, Giuseppe [2 ,3 ]
Matile, Stefan [1 ]
机构：
[1] Univ Geneva, Dept Organ Chem, CH-1211 Geneva, Switzerland
[2] Politecn Milan, NFMLab, I-20131 Milan, Italy
[3] Politecn Milan, CNSC IIT POLIMI Dept Chem Mat & Chem Engn Giulio, I-20131 Milan, Italy
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 49期
基金：
欧洲研究理事会;
关键词：
anions; anion transport; anion-p interactions; halogen bonds; CALIXARENES; SELECTIVITY; RECEPTORS; CHANNEL; SODIUM;
D O I：
10.1002/anie.201104966
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Single-atom exchange series are introduced to extract the individual contributions of halogen bonds and anion-π interactions to the transport of anions across lipid bilayer membranes (see picture). Known cation binding sites are used for counterion activation of the neutral calix[4]arene transporters. The experimental evidence for anion transport with halogen bonds is unprecedented. Copyright © 2011 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码：11675 / 11678
页数：4
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