High proton-conduction in a three-dimensional microporous coordination polymer of Mn(II)

被引：3

作者：

Agarwal, Rashmi A. ^{[1
]}

机构：

[1] Indian Inst Technol, Dept Chem, Kanpur 208016, Uttar Pradesh, India

来源：

INORGANIC CHEMISTRY COMMUNICATIONS | 2016年 / 70卷

关键词：

Supramolecular chemistry; Coordination polymer; Proton conduction; Hydrogen bonding; Thermogravimetry; METAL-ORGANIC FRAMEWORK; TRANSFORMATION; DITHIOOXAMIDE; STATE;

D O I：

10.1016/j.inoche.2016.05.030

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Proton conductivity is shown for a previously reported, porous coordination polymer {[Mn-2(DBIBA)(3)]center dot(NO3)center dot 3DMF center dot 4H(2)O}(n), [DBIBAH = 3,5-di(1H-benzo[d]imidazol-1-yl)benzoic acid] consisting of hexagonal cavities. Nitrate ions and water molecules are present in the central part of the cavity forming a well defined one dimensional extended hydrogen-bonding network. This framework was revealed to be a proton conductor by temperature dependent study at 100% relative humidity (RH). The proton conductivity was 1.64 x 10(-4) S.cm(-1), 2.36 x 10(-4) S.cm(-1) and 3.09 x 10(-4) S.cm(-1) at 30%, 50% and 70% RH respectively. (C) 2016 Elsevier B.V. All rights reserved.

引用

页码：115 / 117

页数：3

共 33 条

[1]

Afshari E., 2009, American Journal of Applied Sciences, V6, P101, DOI 10.3844/ajassp.2009.101.108

[2] Gas Adsorption, Magnetism, and Single-Crystal to Single-Crystal Transformation Studies of a Three-Dimensional Mn(II) Porous Coordination Polymer [J].

Agarwal, Rashmi A. ;

Mukherjee, Soumya ;

Carolina Sanudo, E. ;

Ghosh, Sujit K. ;

Bharadwaj, Parimal K. .

CRYSTAL GROWTH & DESIGN, 2014, 14 (11) :5585-5592

[3]

Alberti G., 2008, MEMBRANE TECHNOLOGY, V2, P97

[4]

Bureekaew S, 2009, NAT MATER, V8, P831, DOI [10.1038/NMAT2526, 10.1038/nmat2526]

[5] Reversible phase transformation in proton conducting Strandberg-type POM based metal organic material [J].

Dey, Chandan ;

Kundu, Tanay ;

Banerjee, Rahul .

CHEMICAL COMMUNICATIONS, 2012, 48 (02) :266-268

[6] Crystallized frameworks with giant pores:: Are there limits to the possible? [J].

Férey, G ;

Mellot-Draznieks, C ;

Serre, C ;

Millange, F .

ACCOUNTS OF CHEMICAL RESEARCH, 2005, 38 (04) :217-225

[7] Powder XRD and solid-state 2H-NMR studies on RAP-protected palladium nanoparticle (RAP = rubeanic-acid polymer) [J].

Fujishima, M. ;

Yamauchi, M. ;

Ikeda, R. ;

Kubo, T. ;

Nakasuji, K. ;

Kitagawa, H. .

SCIENCE AND TECHNOLOGY OF HYBRID MATERIALS, 2006, 111 :107-110

[8]

Fujishima M., 2002, MOL CRYST LIQ CRYST, V379, P581

[9] Galvanostatic transient studies on copper coordination polymer under hydrogen absorption [J].

Fujishima, Musashi ;

Enyo, Michio ;

Kanda, Seiichi ;

Ikeda, Ryuichi ;

Kitagawa, Hiroshi .

CHEMISTRY LETTERS, 2006, 35 (05) :546-547

[10] Coordination-Chemistry Control of Proton Conductivity in the Iconic Metal-Organic Framework Material HKUST-1 [J].

Jeong, Nak Cheon ;

Samanta, Bappaditya ;

Lee, Chang Yeon ;

Farha, Omar K. ;

Hupp, Joseph T. .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2012, 134 (01) :51-54

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