Sensor arrays to detect humic substances and Cu(II) in waters

被引:14
作者
Leite, Fabio L. [2 ,3 ]
Firmino, Alessandra [1 ,2 ]
Borato, Carlos E. [1 ,2 ]
Mattoso, Luiz H. C. [2 ]
da Silva, Wilson T. L. [2 ]
Oliveira, Osvaldo N., Jr. [1 ]
机构
[1] Univ Sao Paulo, Inst Phys Sao Carlos, BR-13560970 Sao Carlos, SP, Brazil
[2] Embrapa Agr Instrumentat, Alan G MacDiarmid Inst Innovat, BR-13560970 Sao Carlos, SP, Brazil
[3] Univ Fed Sao Carlos, BR-18052780 Sorocaba, SP, Brazil
基金
巴西圣保罗研究基金会;
关键词
Humic substances; AFM; Metal complexes; Water; Sensors; Heavy metals; POLY(O-ETHOXYANILINE) NANOSTRUCTURED FILMS; ATOMIC-FORCE SPECTROSCOPY; BY-LAYER FILMS; CONDUCTING POLYMERS; ACID; ADSORPTION; BEHAVIOR;
D O I
10.1016/j.synthmet.2009.07.058
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The interaction between poly(o-ethoxyaniline) (POEA) adsorbed onto solid substrates and humic substances (HS) and Cu2+ ions has been investigated using UV-vis spectroscopy and atomic force microscopy (AFM). Both HS and Cu2+ are able to dope POEA and change film morphology. This interaction was exploited in a sensor array made with nanostructured films of POEA, sulfonated lignin and HS, which could detect small concentrations of HS and Cu2+ in water. (C) 2009 Elsevier B.V. All rights reserved.
引用
收藏
页码:2333 / 2337
页数:5
相关论文
共 25 条
[1]   Layer-by-layer films of poly(o-ethoxyaniline), chitosan and chitosan-poly(methaerylic acid) nanoparticles and their application in an electronic tongue [J].
Borato, Carlos E. ;
Leite, Fabio L. ;
Mattoso, Luiz H. C. ;
Goy, Rejane C. ;
Campana Filho, Sergio P. ;
de Vasconcelos, Claudio L. ;
Neto, Cypriano G. da Trindade ;
Pereira, Marcia R. ;
Fonseca, Jose L. C. ;
Oliveira, Osvaldo N., Jr. .
IEEE TRANSACTIONS ON DIELECTRICS AND ELECTRICAL INSULATION, 2006, 13 (05) :1101-1109
[2]   Efficient taste sensors made of bare metal electrodes [J].
Borato, Carlos E. ;
Leite, Fabio L. ;
Oliveira, Osvaldo N., Jr. ;
Mattoso, Luiz H. C. .
SENSOR LETTERS, 2006, 4 (02) :155-159
[3]   Fabrication and characterization of chemical sensors made from nanostructured films of poly(o-ethoxyaniline) prepared with different doping acids [J].
Brugnollo, E. D. ;
Paterno, L. G. ;
Leite, F. L. ;
Fonseca, F. J. ;
Constantino, C. J. L. ;
Antunes, P. A. ;
Mattoso, L. H. C. .
THIN SOLID FILMS, 2008, 516 (10) :3274-3281
[4]   Immobilization of humic acid in nanostructured layer-by-layer films for sensing applications [J].
Crespilho, FN ;
Zucolotto, V ;
Siqueira, JR ;
Constantino, CJL ;
Nart, FC ;
Oliveira, ON .
ENVIRONMENTAL SCIENCE & TECHNOLOGY, 2005, 39 (14) :5385-5389
[5]  
da Silva WTL, 2002, ELECTROANAL, V14, P71
[6]   Use of conducting polypyrrole blends as gas sensors [J].
de Melo, CP ;
Neto, BB ;
de Lima, EG ;
de Lira, LFB ;
de Souza, JEG .
SENSORS AND ACTUATORS B-CHEMICAL, 2005, 109 (02) :348-354
[7]   Fuzzy nanoassemblies: Toward layered polymeric multicomposites [J].
Decher, G .
SCIENCE, 1997, 277 (5330) :1232-1237
[8]  
*INT HUM SUBST SOC, IS METH IHSS SAMPL
[9]   Colloidal properties of humic substances [J].
Jones, MN ;
Bryan, ND .
ADVANCES IN COLLOID AND INTERFACE SCIENCE, 1998, 78 (01) :1-48
[10]  
Kern W., 1984, Semiconductor International, V7, P94