Nanoparticulate Peroxidase/Catalase Mimetic and Its Application

被引:71
作者
Deng, Huimin [1 ]
Shen, Wei [1 ]
Peng, Yanfen [2 ]
Chen, Xiaojun [2 ]
Yi, Guangshun [2 ]
Gao, Zhiqiang [1 ]
机构
[1] Natl Univ Singapore, Dept Chem, Singapore 117543, Singapore
[2] Inst Bioengn & Nanotechnol, Singapore 138669, Singapore
关键词
catalases; catalysis; enzyme mimetics; nanoparticles; ruthenium oxide; FUNCTIONALIZED GOLD NANOPARTICLES; MAGNETIC NANOPARTICLES; OXIDE NANOPARTICLES; CATALYSTS; ACID; POLYANILINE; CATALASES; DIVERSITY; NANOZYMES; H2O2;
D O I
10.1002/chem.201200643
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Ru sitting comfortably: Ruthenium oxide nanoparticles show bienzyme-like activities, and are capable of catalyzing H 2O 2 disproportionation at pH 7.0 and peroxidation at pH 4.0 in aqueous solutions (see scheme). Their specific activities are better than many natural catalases and peroxidases and far better than bifunctional catalase/peroxidases. © 2012 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
引用
收藏
页码:8906 / 8911
页数:6
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