An electrochromic and fluorescent polymer based on 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole

被引：63
作者：
Cihaner, Atilla [1 ]
Algi, Fatih [2 ]
机构：
[1] Atilim Univ, Chem Grp, Fac Engn, TR-06836 Ankara, Turkey
[2] Canakkale Onsekiz Mart Univ, Dept Chem, TR-17100 Canakkale, Turkey
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2008年 / 614卷 / 1-2期
关键词：
electrochemical polymerization; polythiophene; polypyrrole; naphthalene;
D O I：
10.1016/j.jelechem.2007.11.024
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A novel polymer was synthesized by electrochemical polymerization of 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole (SNS-1-NAPH). The corresponding polymer (PSNS-1-NAPH) was characterized by cyclic voltammetry, FT-IR and UV-vis spectroscopy. The polymer has a very well-defined and reversible redox process in both organic and aqueous solutions. Furthermore, it shows stable electrochromic behavior; yellow in the neutral state, green in the intermediate state and violet in the oxidized state. PSNS-1-NAPH is soluble in common solvents. Although SNS-1-NAPH is almost nonfluorescent, its polymer is a yellow and/or green light emitter. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：101 / 106
页数：6
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