An electrochromic and fluorescent polymer based on 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole

被引：63
|
作者：
Cihaner, Atilla [1 ]
Algi, Fatih [2 ]
机构：
[1] Atilim Univ, Chem Grp, Fac Engn, TR-06836 Ankara, Turkey
[2] Canakkale Onsekiz Mart Univ, Dept Chem, TR-17100 Canakkale, Turkey
来源：
JOURNAL OF ELECTROANALYTICAL CHEMISTRY | 2008年 / 614卷 / 1-2期
关键词：
electrochemical polymerization; polythiophene; polypyrrole; naphthalene;
D O I：
10.1016/j.jelechem.2007.11.024
中图分类号：
O65 [分析化学];
学科分类号：
070302 ; 081704 ;
摘要：
A novel polymer was synthesized by electrochemical polymerization of 1-(1-naphthyl)-2,5-di-2-thienyl-1H-pyrrole (SNS-1-NAPH). The corresponding polymer (PSNS-1-NAPH) was characterized by cyclic voltammetry, FT-IR and UV-vis spectroscopy. The polymer has a very well-defined and reversible redox process in both organic and aqueous solutions. Furthermore, it shows stable electrochromic behavior; yellow in the neutral state, green in the intermediate state and violet in the oxidized state. PSNS-1-NAPH is soluble in common solvents. Although SNS-1-NAPH is almost nonfluorescent, its polymer is a yellow and/or green light emitter. (c) 2007 Elsevier B.V. All rights reserved.
引用
收藏
页码：101 / 106
页数：6
相关论文
共 50 条
  • [1] Electrochemical polymerization of tetramethylene-crosslinked bis(2,5-di-2-thienyl-1H-pyrrole)
    Ono, K
    Totani, H
    Ohkita, M
    Saito, K
    Kato, M
    HETEROCYCLES, 2004, 64 : 223 - 228
  • [2] A soluble conducting polymer: 1-phenyl-2,5-di(2-thienyl)-1H-pyrrole and its electrochromic application
    Tarkuc, S.
    Sahmetlioglu, E.
    Tanyeli, C.
    Akhmedov, I. M.
    Toppare, L.
    ELECTROCHIMICA ACTA, 2006, 51 (25) : 5412 - 5419
  • [3] Immobilization of invertase on a conducting polymer of 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H-pyrrole
    Tuncagil, Sevinc
    Kiralp, Senem
    Varls, Serhat
    Toppare, Levent
    REACTIVE & FUNCTIONAL POLYMERS, 2008, 68 (03): : 710 - 717
  • [4] Design of a biosensor based on 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H pyrrole
    Tuncagil, Sevinc
    Varis, Serhat
    Toppare, Levent
    JOURNAL OF MOLECULAR CATALYSIS B-ENZYMATIC, 2010, 64 (3-4) : 195 - 199
  • [5] Electrochemical and Electrochromic Properties of Polymers Based on 2,5-di(2-thienyl)-1H-pyrrole and Different Phenothiazine Units
    Hu, Bin
    Li, Chun-yang
    Chu, Jun-wei
    Liu, Zeng-chen
    Zhang, Xin-lei
    Jin, Lin
    JOURNAL OF THE ELECTROCHEMICAL SOCIETY, 2019, 166 (02) : H1 - H11
  • [6] A novel multielectrochromic copolymer based on 1-(4-nitrophenyl)-2,5-di(2-thienyl)-1H-pyrrole and EDOT
    Varis, Serhat
    Ak, Metin
    Akhmedov, Iris M.
    Tanyeli, Cihangir
    Toppare, Levent
    JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 603 (01) : 8 - 14
  • [7] Electrochromic properties of a soluble conducting polymer:: Poly(1-(4-fluorophenyl)-2,5-di(thiophen-2-yl)-1H-pyrrole)
    Arslan, Ahu
    Tuerkarslan, Oezlem
    Tanyeli, Cihangir
    Akhmedov, Idris Mecidoglu
    Toppare, Levent
    MATERIALS CHEMISTRY AND PHYSICS, 2007, 104 (2-3) : 410 - 416
  • [8] (S)-(+)-1-(1-Naphthyl)-1-(2-thienylmethylene)ethylamine
    Espinosa Leija, Armando
    Hernandez, Guadalupe
    Portillo, Roberto
    Gutierrez, Rene
    Bernes, Sylvain
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2009, 65 : 01651 - U3095
  • [9] STRUCTURE OF 1-(1-NAPHTHYL)-1H-1,2,3-TRIAZOLE
    NAGAWA, Y
    GOTO, M
    HONDA, K
    NAKANISHI, H
    ACTA CRYSTALLOGRAPHICA SECTION C-CRYSTAL STRUCTURE COMMUNICATIONS, 1987, 43 : 147 - 149
  • [10] 1-(Acetylphenyl)-2,5-dimethyl-1H-pyrrole
    Santos, Ana C.
    Marques, Ana T.
    Silva, Manuela Ramos
    Beja, Ana Matos
    Sobral, Abilio J. F. N.
    ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O4233 - U2598
12345