Determination of ferroelastic phase transition temperature in BiVO4 by Raman spectroscopy

被引：19

作者：

Kshetri, Yuwaraj K. ^{[1
]}

Chaudhary, Bina ^{[2
]}

Kamiyama, Takashi ^{[3
]}

Kim, Tae-Ho ^{[2
]}

Rosei, Federico ^{[4
]}

Lee, Soo Wohn ^{[5
]}

机构：

[1] Sun Moon Univ, Res Ctr Ecomultifunct Nano Mat, Chungnam, South Korea

[2] Sun Moon Univ, Dept Fus Sci & Technol, Chungnam, South Korea

[3] KEK, Inst Mat Struct Sci, J PARC Ctr, Tokai, Ibaraki 3191106, Japan

[4] Inst Natl Rech Sci, 1650 Blvd Lionel Boulet, Varennes, PQ, Canada

[5] Sun Moon Univ, Dept Environm & Biochem Engn, Chungnam, South Korea

来源：

MATERIALS LETTERS | 2021年 / 291卷

基金：

新加坡国家研究基金会;

关键词：

BiVO4; Raman spectroscopy; Ferroelastic phase transition; SINGLE-CRYSTALS; GROWTH; FILMS;

D O I：

10.1016/j.matlet.2021.129519

中图分类号：

T [工业技术];

学科分类号：

08 ;

摘要：

BiVO4, a well-known photocatalyst and industrial pigment, undergoes a reversible ferroelastic phase transition at about 530 K. In this framework, identifying techniques that can accurately measure the signature of the ferroelastic phase transition would be very useful. We find that the most intense Raman band of BiVO4 ceramics at 829 cm(-1) shows an interesting temperature dependency, as it is non-linear in the investigated range of 298-898 K, while two distinct linear regimes can be distinguished below and above 550 K. The point of the intersection after extrapolating the two linear regions is 530 K, which happens to be the ferroelastic phase transition temperature of BiVO4 from monoclinic to tetragonal phase. (C) 2021 Elsevier B.V. All rights reserved.

引用

页数：4

共 16 条

[1] FERROELASTICITY IN BIVO4 [J].

BIERLEIN, JD ;

SLEIGHT, AW .

SOLID STATE COMMUNICATIONS, 1975, 16 (01) :69-70

[2]

David W. I. F., 1979, Phase Transitions, V1, P155, DOI 10.1080/01411597908213198

[3] FERROELASTIC PHASE-TRANSITION IN BIVO4 .5. TEMPERATURE-DEPENDENCE OF BI-3+ DISPLACEMENT AND SPONTANEOUS STRAINS [J].

DAVID, WIF ;

WOOD, IG .

JOURNAL OF PHYSICS C-SOLID STATE PHYSICS, 1983, 16 (26) :5127-5148

[4] Raman spectroscopy of three polymorphs of BiVO4:: clinobisvanite, dreyerite and pucherite, with comparisons to (VO4)3-bearing minerals:: namibite, pottsite and schumacherite [J].

Frost, Ray L. ;

Henry, Dermot A. ;

Weier, Matt L. ;

Martens, Wayde .

JOURNAL OF RAMAN SPECTROSCOPY, 2006, 37 (07) :722-732

[5] VANADIUM(V) ENVIRONMENTS IN BISMUTH VANADATES - A STRUCTURAL INVESTIGATION USING RAMAN-SPECTROSCOPY AND SOLID-STATE V-51 NMR [J].

HARDCASTLE, FD ;

WACHS, IE ;

ECKERT, H ;

JEFFERSON, DA .

JOURNAL OF SOLID STATE CHEMISTRY, 1991, 90 (02) :194-210

[6] EFFECT OF H-2 DILUTION ON THE GROWTH OF LOW-TEMPERATURE AS-DEPOSITED POLY-SI FILMS USING SIF4/SIH4/H-2 PLASMA [J].

KIM, SK ;

PARK, KC ;

JANG, J .

JOURNAL OF APPLIED PHYSICS, 1995, 77 (10) :5115-5118

[7] Ferroelastic Phase Transition of BiVO4 Single Crystals with Prominent W-Domain Walls by Stress-Strain Hysteresis Measurements [J].

Lim, Ae Ran ;

Jeong, Se-Young .

JOURNAL OF INTELLIGENT MATERIAL SYSTEMS AND STRUCTURES, 2010, 21 (09) :915-920

[8] FERROELASTIC PHASE-TRANSITION OF BIVO4 STUDIED BY V-51 NMR [J].

LIM, AR ;

CHOH, SH ;

JANG, MS .

FERROELECTRICS, 1989, 94 (01) :389-394

[9] Phase transition systematics in BiVO4 by means of high-pressure-high-temperature Raman experiments [J].

Pellicer-Porres, J. ;

Vazquez-Socorro, D. ;

Lopez-Moreno, S. ;

Munoz, A. ;

Rodriguez-Hernandez, P. ;

Martinez-Garcia, D. ;

Achary, S. N. ;

Rettie, A. J. E. ;

Mullins, C. Buddie .

PHYSICAL REVIEW B, 2018, 98 (21)

[10] SOFT OPTICAL PHONON IN FERROELASTIC BIVO4 [J].

PINCZUK, A ;

BURNS, G ;

DACOL, FH .

SOLID STATE COMMUNICATIONS, 1977, 24 (02) :163-165

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