Experimental critical constants, vapor pressures, and vapor and liquid densities for pentafluoroethane (R-125)

被引:23
作者
DuarteGarza, HA
Stouffer, CE
Hall, KR
Holste, JC
Marsh, KN
Gammon, BE
机构
[1] TEXAS A&M UNIV,DEPT CHEM ENGN,COLLEGE STN,TX 77843
[2] TEXAS A&M UNIV SYST,THERMODYNAM RES CTR,COLLEGE STN,TX 77843
关键词
D O I
10.1021/je960362f
中图分类号
O414.1 [热力学];
学科分类号
摘要
This paper presents measurements of vapor pressure from 220 K to 338 K, liquid density from 180 K to 350 K and up to 70 MPa and vapor density from 310 K to 480 K and up to 12 MPa for pentafluoroethane (R-125). Extrapolating the observed vapor pressures to the measured critical temperature (339.41 +/- 0.01) K provides a critical pressure of (3.6391 +/- 0.002) MPa. Using these values with the law of rectilinear diameters indicates a critical density of (4768 +/- 7) mol.m(-3) Correlations provide values which agree with the measured values for the vapor densities within +/- 0.05%, the liquid densities within +/- 0.1%, and the vapor pressures within +/- 0.05%. The results are compared with values from the Literature.
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收藏
页码:745 / 753
页数:9
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