Rare example of structurally characterized mononuclear N-heterocyclic carbene containing zinc carboxylate

被引：8

作者：

Yambulatov, Dmitriy S. ^{[1
]}

Petrov, Pavel A. ^{[2
,3
]}

Nelyubina, Yulia V. ^{[1
,4
]}

Starikova, Alyona A. ^{[5
]}

Pavlov, Alexander A. ^{[4
]}

Aleshin, Dmitry Yu. ^{[4
]}

Nikolaevskii, Stanislav A. ^{[1
]}

Kiskin, Mikhail A. ^{[1
]}

Sokolov, Maxim N. ^{[2
,3
]}

Eremenko, Igor L. ^{[1
,4
]}

机构：

[1] Russian Acad Sci, NS Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

[2] Russian Acad Sci, Siberian Branch, AV Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia

[3] Novosibirsk State Univ, Novosibirsk 630090, Russia

[4] Russian Acad Sci, AN Nesmeyanov Inst Organoelement Cpds, Moscow 119991, Russia

[5] Southern Fed Univ, Inst Phys & Organ Chem, Rostov Na Donu 344090, Russia

来源：

MENDELEEV COMMUNICATIONS | 2020年 / 30卷 / 03期

基金：

俄罗斯科学基金会;

关键词：

N-heterocyclic carbenes; carboxylate complexes; zinc(II); DFT calculations; X-ray crystallography; COMPLEXES; CO2; NHC;

D O I：

10.1016/j.mencom.2020.05.010

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

An adduct of Zn-II pivalate with N-heterocyclic carbene 1,3-bis(2,4,6-trimethylphenyl)imidazol-2-ylidene has been prepared and characterized by X-ray diffraction analysis, NMR spectroscopy and DFT calculations. The compound preserves mononuclear structure in solution and does not switch the coordination mode from normal to abnormal.

引用

页码：293 / 295

页数：3

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