Solar-driven CO2 to CO reduction utilizing H2O as an electron donor by earth-abundant Mn-bipyridine complex and Ni-modified Fe-oxyhydroxide catalysts activated in a single-compartment reactor

被引：39

作者：

Arai, Takeo ^{[1
]}

Sato, Shunsuke ^{[1
]}

Sekizawa, Keita ^{[1
]}

Suzuki, Tomiko M. ^{[1
]}

Morikawa, Takeshi ^{[1
]}

机构：

[1] Toyota Cent Res & Dev Labs Inc, 41-1 Yokomichi, Nagakute, Aichi 4801192, Japan

来源：

CHEMICAL COMMUNICATIONS | 2019年 / 55卷 / 02期

基金：

日本科学技术振兴机构;

关键词：

WATER OXIDATION; EFFICIENT; ELECTROCATALYSTS; PHOTOREDUCTION; NICKEL;

D O I：

10.1039/c8cc07900e

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Photoelectrochemical CO2 to CO reduction was demonstrated with 3.4% solar-to-chemical conversion efficiency using polycrystalline silicon photovoltaic cells connected with earth-abundant catalysts: a manganese complex polymer for CO2 reduction and iron oxyhydroxide modified with a nickel compound for water oxidation. The system operated around neutral pH in a single-compartment reactor.

引用

页码：237 / 240

页数：4

共 24 条

[1] A monolithic device for CO2 photoreduction to generate liquid organic substances in a single-compartment reactor [J].

Arai, Takeo ;

Sato, Shunsuke ;

Morikawa, Takeshi .

ENERGY & ENVIRONMENTAL SCIENCE, 2015, 8 (07) :1998-2002

[2] Revised Pourbaix diagrams for nickel at 25-300 degrees C [J].

Beverskog, B ;

Puigdomenech, I .

CORROSION SCIENCE, 1997, 39 (05) :969-980

[3] Amorphous FeOOH Oxygen Evolution Reaction Catalyst for Photoelectrochemical Water Splitting [J].

Chemelewski, William D. ;

Lee, Heung-Chan ;

Lin, Jung-Fu ;

Bard, Allen J. ;

Mullins, C. Buddie .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2014, 136 (07) :2843-2850

[4] The importance of nickel oxyhydroxide deprotonation on its activity towards electrochemical water oxidation [J].

Diaz-Morales, Oscar ;

Ferrus-Suspedra, David ;

Koper, Marc T. M. .

CHEMICAL SCIENCE, 2016, 7 (04) :2639-2645

[5] Guidelines for the Rational Design of Ni-Based Double Hydroxide Electrocatalysts for the Oxygen Evolution Reaction [J].

Diaz-Morales, Oscar ;

Ledezma-Yanez, Isis ;

Koper, Marc T. M. ;

Calle-Vallejo, Federico .

ACS CATALYSIS, 2015, 5 (09) :5380-5387

[6] Tracking Catalyst Redox States and Reaction Dynamics in Ni-Fe Oxyhydroxide Oxygen Evolution Reaction Electrocatalysts: The Role of Catalyst Support and Electrolyte pH [J].

Goerlin, Mikaela ;

de Araujo, Jorge Ferreira ;

Schmies, Henrike ;

Bernsmeier, Denis ;

Dresp, Soeren ;

Gliech, Manuel ;

Jusys, Zenonas ;

Chernev, Petko ;

Kraehnert, Ralph ;

Dau, Holger ;

Strasser, Peter .

JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (05) :2070-2082

[7] Dynamical changes of a Ni-Fe oxide water splitting catalyst investigated at different pH [J].

Goerlin, Mikaela ;

Gliech, Manuel ;

de Araujo, Jorge Ferreira ;

Dresp, Soeren ;

Bergmann, Arno ;

Strasser, Peter .

CATALYSIS TODAY, 2016, 262 :65-73

[8] Mechanistic aspects of CO2 reduction catalysis with manganese-based molecular catalysts [J].

Grills, David C. ;

Ertem, Mehmed Z. ;

McKinnon, Meaghan ;

Ngo, Ken T. ;

Rochford, Jonathan .

COORDINATION CHEMISTRY REVIEWS, 2018, 374 :173-217

[9]

Haining T., 2015, CHEMSUSCHEM, V8, P3746

[10] Photochemical and Photoelectrochemical Reduction of CO2 [J].

Kumar, Bhupendra ;

Llorente, Mark ;

Froehlich, Jesse ;

Dang, Tram ;

Sathrum, Aaron ;

Kubiak, Clifford P. .

ANNUAL REVIEW OF PHYSICAL CHEMISTRY, VOL 63, 2012, 63 :541-+

← 1 2 3 →