Photodegradation of Methyl Orange under Visible Light by Micro-Nano Hierarchical Cu2O Structure Fabricated by Hybrid Laser Processing and Chemical Dealloying

被引:75
作者
Dong, Changsheng [1 ]
Zhong, Minlin [1 ]
Huang, Ting [1 ]
Ma, Mingxing [1 ]
Wortmann, Dirk [2 ]
Brajdic, Mihael [2 ]
Kelbassa, Ingomar [2 ]
机构
[1] Tsinghua Univ, Dept Mech Engn, Key Lab Adv Mat Proc Technol, Minist Educ, Beijing 100084, Peoples R China
[2] Rhein Westfal TH Aachen, Fraunhofer Inst Laser Technol ILT, D-52074 Aachen, Germany
基金
中国国家自然科学基金;
关键词
micro-nano hierarchical structure; photo degradation; laser ablation; dealloying; PHOTOCATALYTIC DEGRADATION; NANOPOROUS GOLD; THIN-FILM; TIO2; COPPER; NANOPARTICLES; EVOLUTION; OXIDE;
D O I
10.1021/am200997w
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Micro-nano hierarchical structure on the substrate was fabricated by a hybrid approach including laser deposition, laser ablation and chemical dealloying. The structure consists of micro bumps with a width of 50 mu m and a height of 100 mu m, and nanoporous structures with a size of 70-150 nm on the micro bumps. XRD and XPS results confirm that these hierarchical structures were made of Cu2O. For use in comparison, three additional structures with feature size in milliscale, microscale, and nanoscale were also prepared respectively by the proposed methods. Under visible light, the micro-nano structure exhibited the best performance of photodegradation. It is the result of the large specific surface and the catalytic reaction driven by the cuprous oxides.
引用
收藏
页码:4332 / 4338
页数:7
相关论文
共 34 条
[1]  
AHMAD U, 2011, J NANOSCI NANOTECHNO, V4, P3474
[2]   Role of Cu in the Cu-TiO2 photocatalytic degradation of dihydroxybenzenes [J].
Araña, J ;
Rodríguez, CF ;
Díaz, OG ;
Melián, JAH ;
Peña, JP .
CATALYSIS TODAY, 2005, 101 (3-4) :261-266
[3]   Hydrogels and Aerogels from Noble Metal Nanoparticles [J].
Bigall, Nadja C. ;
Herrmann, Anne-Kristin ;
Vogel, Maria ;
Rose, Marcus ;
Simon, Paul ;
Carrillo-Cabrera, Wilder ;
Dorfs, Dirk ;
Kaskel, Stefan ;
Gaponik, Nikolai ;
Eychmueller, Alexander .
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (51) :9731-9734
[4]   Morphology and Structure of Aerosol Carbon-Encapsulated Metal Nanoparticles from Various Ambient Metal-Carbon Spark Discharges [J].
Byeon, Jeong Hoon ;
Kim, Jang-Woo .
ACS APPLIED MATERIALS & INTERFACES, 2010, 2 (04) :947-951
[5]   Nanoporous Copper with Tunable Nanoporosity for SERS Applications [J].
Chen, Lu-Yang ;
Yu, Jin-Shan ;
Fujita, Takeshi ;
Chen, Ming-Wei .
ADVANCED FUNCTIONAL MATERIALS, 2009, 19 (08) :1221-1226
[6]   Nanoporous gold leaf: "Ancient technology"/advanced material [J].
Ding, Y ;
Kim, YJ ;
Erlebacher, J .
ADVANCED MATERIALS, 2004, 16 (21) :1897-+
[7]   Fabrication of superhydrophobic Cu surfaces with tunable regular micro and random nano-scale structures by hybrid laser texture and chemical etching [J].
Dong, Changsheng ;
Gu, Yu ;
Zhong, Minlin ;
Li, Lin ;
Sezer, Kursad ;
Ma, Mingxing ;
Liu, Wenjin .
JOURNAL OF MATERIALS PROCESSING TECHNOLOGY, 2011, 211 (07) :1234-1240
[8]   Evolution of nanoporosity in dealloying [J].
Erlebacher, J ;
Aziz, MJ ;
Karma, A ;
Dimitrov, N ;
Sieradzki, K .
NATURE, 2001, 410 (6827) :450-453
[9]   Fabrication of novel comb-like Cu2O nanorod-based structures through an interface etching method and their application as ethanol sensors [J].
Guan, Lina ;
Pang, Huan ;
Wang, Jianjun ;
Lu, Qingyi ;
Yin, Jingzhou ;
Gao, Feng .
CHEMICAL COMMUNICATIONS, 2010, 46 (37) :7022-7024
[10]  
Herrmann T, 2006, ICALEO 2006 25 INT C, P304